A new system of chemical philosophy, Volume 2, Part 1Dalton, John
Science
A new system of chemical philosophy, Volume 2, Part 1
Dalton, John
Atomic theory; Chemistry, Inorganic
One difficulty seems to have occurred to M. M. Dulong and Petit. They
all along conceive that the specific heats of bodies, that is, the
heats producing equal increments of temperature, must necessarily
be proportionate to their whole heat. This is purely hypothetical,
till established by experiment. The generality of writers on specific
heat had conceived it almost confirmed by experiment. The results of
Delaroche and Berard have shewn that in elastic fluids the increments
of heat are not proportional to the whole quantities, but on the
contrary are less when a body is elastic than when liquid. Indeed
some writers have argued this should be the case; because a body
nearly saturated with another has less affinity for it left.[27] It
is plain then that oxygen gas or any other elastic fluid, may have a
small specific heat in the sense above defined, and yet have an almost
unlimited quantity of heat. I am not aware of any one established
fact that does not admit of an explanation upon the hypothesis that
heat exists in definite quantities in all bodies, and is incapable of
any change, except perhaps into one of the other equally imponderable
bodies, light or electricity.
[Footnote 27: See Dr. Henry’s note, Manch. Memoirs, vol. 5, page 679.]
NEW TABLE OF THE
_Forces of Vapours in Contact with the
Generating Liquids at Different Temperatures._
(A) = Temperatures by the common thermometer.
(B) = Ether vapour, ratio 2 Spec. Gravity .72
(C) = Sulphuret of carbon vapour, ratio 1.978
(D) = Alcohol vapour, ratio 2.7 Spec. Gravity .82
(E) = Acetic acid vapour, ratio 2.57
(F) = Water, ratio 2.602()
-----+--------+--------+--------+--------+-------
(A) | (B) | (C) | (D) | (E) | (F)
-----+--------+--------+--------+--------+-------
| Inches | Inches | Inches | Inches |Inches
| of M. | of M. | of M. | of M. | of M.
-----+--------+--------+--------+--------+-------
7° | 3.75 | 3.134 | .193 | | .11
35 | 7.5 | 6.20 | .560 | .27 | .29
65+ | 15. | 12.26 | 1.51 | .69 | .75
97 | 30 | 24.26 | 4.07 | 1.77 | 1.95
133 | 60 | 48. | 11.00 | 4.54 | 5.07
173 | 120 | | 29.70 | 11.7 | 13.18
220 | 240 | | 80.2 | 30. | 34.2
272 | | | | | 88.9
340 | | | | | 231
-----+--------+--------+--------+--------+-------
This is an improved and extended table of the force
of vapour, similar to that at page 14, vol. I. It
shews that the different vapours increase inforce
in geometrical progression, to certain intervals
of temperature, the same to most or all liquids.
These intervals of temperature were presumed in the
former table, to be in reality _equal_ to one
another; but the accuracy of this last notion has been
questioned.
Public-domain text, read in full here on John Shaqi.
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