A new system of chemical philosophy, Volume 2, Part 1Dalton, John
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A new system of chemical philosophy, Volume 2, Part 1
Dalton, John
Atomic theory; Chemistry, Inorganic
Real nitric acid then is that combination which is effected by uniting
oxygen with a minimum of nitrous gas; or 1 measure of oxygen with
1.3 nitrous gas, (See Vol. 1, page 328). The oxynitric acid, which I
was led to infer from the last mentioned combination, (1 azote with
3 oxygen) does not appear to exist. The Table of nitric acid (Vol.
1, page 355) will require some correction. An increase of about 4
per cent. should be made, I apprehend, on the quantities of acid
corresponding to the several specific gravities.
Since my former volume of Chemistry was printed, several essays on
the compounds of azote and oxygen have been published, with some new
and some additional experiments, the chief of which may be seen in
Sir H. Davy’s Elements of Chemical Philosophy, the Annales de chimie
et de physique, Vol. 1; Annals of philosophy, Vol. 9 and 10; and
the Manchester Society’s Memoirs, Vol. 4, _second series_; also Dr.
Thomson’s first principles of Chemistry. Notwithstanding all that has
been written on the subject, there still appears uncertainty as to the
number of combinations formed by these two elements, their relative
weights, and the number of atoms in the several compounds.
The results of an experiment I lately made on the decomposition
of nitrate of potash by heat seem to be worthy of record, as I am
not acquainted with those of any other person who has pursued the
experiment to the same extent.--I took an iron retort of 6 cubic inches
capacity, and cleaned it as well as I could from carbonaceous matter
which it had previously contained, first by heating nitre to redness
for an hour or more in it, and then washing it repeatedly with water
till the liquid came out tasteless, and only mixed with a little red
rust; I then put in 480 grains of purified nitre, and having secured
a copper tube to the retort so as to be air tight, the retort was put
into a fire and gradually raised to a red heat, and the fire was
occasionally urged with a pair of bellows, in order to keep up a
glowing red on the retort for nearly two hours; the air was received
over water in jars; the first 4 or 5 inches were thrown away, and the
rest was preserved and transferred to a graduated jar; the products
were examined in successive portions as under, namely,
Inches.
1 produce, 85 cubic inches, 83 per cent. pure = 70.5
2 5 77 = 3.85
3 25 50 = 12.5
4 6 30 = 1.8
----- -------
Total 121 Oxygen 88.65
Oxygen 88.65 = 30 grains.
------
Residue 32.35 = 10 grains.
About 1 per cent. on the whole gas was carbonic acid, the rest oxygen
and azote, the weights of which would be nearly as above.
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