A new system of chemical philosophy, Volume 2, Part 1Dalton, John
Science
A new system of chemical philosophy, Volume 2, Part 1
Dalton, John
Atomic theory; Chemistry, Inorganic
Three notions have been submitted to the public in the last twenty
years in regard to the nature of muriatic acid. First, the gas detached
from common salt by sulphuric acid has been thought to be the acid in
a state of purity, and constituted of a certain base or radical united
to oxygen; this was the notion inculcated in the articles alluded to
above. Second,--it is stated as a fact that when oxymuriatic acid and
hydrogen in equal volumes are united by the electric spark, a volume
of muriatic acid gas is the result equal to the sum of both the other
volumes, and that this gas perfectly agrees with the gas obtained from
common salt by sulphuric acid; this suggested the idea that muriatic
acid gas is a compound of what has been called _real_ or _dry_ muriatic
acid one atom, and water one atom. And, third, it is argued, that
the element we have called oxymuriatic acid gas, is, for aught that
appears, a _simple_ body, and consequently, that muriatic acid gas is
the _real acid_, and is constituted as above, of one atom of hydrogen,
and one atom of oxymuriatic acid (now called _chlorine_.) It is not
intended here to enter into a discussion of the arguments and facts
adduced in support of the different conclusions. More experience
must be had before all the doubts and difficulties are removed from
the subject. But it will be proper to illustrate these different
positions by an example. For instance, common salt, muriate of soda or
chloride of sodium. By the first notion 50 parts of dry common salt
will consist of one atom of muriatic acid gas, 22, and one atom of
caustic soda, 28. By the second notion the same salt will be formed of
30 parts of muriatic acid gas, and 28 of caustic soda; but 8 parts of
water evaporate when the salt is dried. By the third view common salt
consists of oxymuriatic acid, or chlorine and sodium, or the metal of
which caustic soda is the protoxide; and 50 parts of salt will consist
of 29 chlorine and 21 sodium, or one atom of each.
NITRIC ACID--COMPOUNDS OF AZOTE AND OXYGEN.
Since the account of nitric acid (Vol. 1, page 343) was printed, a
change has universally taken place in estimating the weight of the
nitric acid atom, and of the proportion of azote and oxygen in the
same. This has been effected chiefly by a more correct analysis of
nitre than existed at that time. Nitre is now found to consist nearly
of 52 parts acid and 48 parts potash per cent. Hence if the atom of
potash be 42, that of nitric acid must be 45; for, 48 ∶ 52 ∷ 42 ∶ 45,
nearly. That is, the nitric acid atom consists of 10 azote + 35 oxygen
by weight; or of 2 atoms of azote (according to my estimate) and 5 of
oxygen. There appear to be _two_ nitrous acids; namely, the one which I
have designated by that name, which may now be called _subnitrous_, or
as Gay Lussac terms it _pernitrous_; and the other what I considered as
_nitric acid_ in the former volume, composed of 1 atom azote, and 2 of
oxygen.
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