A new system of chemical philosophy, Volume 2, Part 1Dalton, John
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A new system of chemical philosophy, Volume 2, Part 1
Dalton, John
Atomic theory; Chemistry, Inorganic
In pursuing this enquiry into the decomposition of nitrous gas
by combustible gases, I found that it might be effected by any
combustible gas or vapour: at least it succeeded in all I tried. The
method I pursued, and which was suggested by the known properties of
phosphuretted hydrogen, is this: it has been shewn (page 181) that
a mixture of phosphuretted hydrogen and nitrous gas exploded by an
electric spark, the former gas being completely burned in case the
proportions are duly adjusted; now, it occurred to me, that as the
above combustible gas is usually a mixture of pure phosphuretted
hydrogen and of hydrogen, and that the latter of these is also
burned as well as the former, the effect must be produced through
the heat occasioned by the combustion of the former. Having some old
phosphuretted hydrogen by me, at the time, which on examination, I
found to be 91 per cent. combustible gas, and 9 azote; and the 91
combined with 156 of oxygen, consequently was 74 pure, and 17 hydrogen;
I tried this mixture with nitrous gas, when it exploded by the spark,
as usual; but on trying it with an excess or defect of nitrous gas, the
spark was inefficient, but the shock instantly fired the mixture. As
there did not appear to be any of the pure hydrogen left unburned in
these experiments, I proceeded to mix the old phosphuretted hydrogen
with hydrogen; and then this new mixture with nitrous gas. The first
experiment was made with 4 parts of old phosphuretted hydrogen + 16
hydrogen + 36 nitrous gas = 56 total. On this mixture the spark, of
course, had no effect; but it exploded the first trial by the jar, and
left 20 measures, of which 2 were found to be oxygen, and the rest
azote. This experiment succeeding so well, I next tried mixtures of
phosphuretted hydrogen, with carbonic oxide, carburetted hydrogen, and
ether vapour successively, along with nitrous gas; and found that all
these mixtures refused combustion by the spark, but were instantly
exploded by the shock, yielding carbonic acid and water, the same as if
the combustion had been effected by free oxygen. In some instances the
combustion was complete, leaving neither combustible gas nor nitrous
gas; but generally there was a residue of one or both of the gases.
Public-domain text, read in full here on John Shaqi.
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