A new system of chemical philosophy, Volume 2, Part 1Dalton, John
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A new system of chemical philosophy, Volume 2, Part 1
Dalton, John
Atomic theory; Chemistry, Inorganic
From these experiments it may be concluded that the heat, produced by
the combustion of phosphuretted hydrogen and nitrous gas or oxygen
gas, disposes other gases, accidentally in the mixture, to chemical
changes. In conformity with this view, I mixed phosphuretted hydrogen
and oxygen, in the proportion of mutual saturation; and taking a
small proportion of this mixture, and as much ammoniacal gas as would
saturate the phosphoric acid to be formed, I found that causing an
explosion over mercury, the phosphoric acid combined with the ammonia,
and nearly the whole gas disappeared. In this case, the heat was not
sufficient to decompose the ammonia. But in another experiment, with a
portion of the same explosive mixture and a less proportion of ammonia,
after the firing a residue of azote and hydrogen was found, amounting
nearly to the quantity due from the decomposition of the ammonia. Here
the heat produced, had evidently decomposed the ammonia.
ON AMMONIA.
The constitution of ammonia still remains undecided. The latest
experiments on this article are those of Dr. Henry, in his essay on
the analysis of the compounds of nitrogen. (Memoirs of the Manchester
Society, vol. 4, 1824.) By electrifying ammoniacal gas over mercury, as
carefully as could be devised, Dr. Henry found results as under:
1st experiment 44 measures became 88+
2d 157 320
3d 60 122
4th 120 240
The evolved gases carefully analysed by combustion with oxygen, were
found to consist of 3 volumes of hydrogen and 1 of azote. The analysis
of ammonia was also effected by exploding it with nitrous oxide, with
the requisite precautions. The results confirmed the previous ones
by electricity, both in regard to doubling the volume of ammonia,
and establishing the ratio of 3 to 1 in the volume of hydrogen and
azote.--These experiments are highly interesting as far as regards the
question of ammonia, as they exhibit the latest investigations of one
who has previously shewn uncommon skill and perseverance in this kind
of analysis. (See Philos. Transact. 1809, &c.)
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