A new system of chemical philosophy, Volume 2, Part 1Dalton, John
Science
A new system of chemical philosophy, Volume 2, Part 1
Dalton, John
Atomic theory; Chemistry, Inorganic
One source of uncertainty in these experiments on firing mixtures of
ammonia, is that the real quantity of ammoniacal gas operated upon
is not known. If a certain measure of ammonia be transferred through
mercury ever so dry, some portion of it gets entangled in the mercury,
and 100 measures become perhaps 95: now in the explosion it is a
question whether any part of the 5 measures absorbed is decomposed.
I have marked this attentively, and am persuaded that generally
speaking, little if any of that portion is decomposed; but some trace
of it appears mostly afterwards in the residue as it is liberated from
the pressure of its own kind of gas, and hence easily rises into the
gaseous mixture. Notwithstanding, when the loss of gas by transfer
amounts to 10 or 20 per cent., I have reason to believe that some part
of it suffers combustion occasionally.
_Volume of gases from the decomposition of ammonia._--It has been
observed (vol. 1. Ammonia) that Sir H. Davy obtained 180 measures of
gases, by means of electricity, from 100 of ammonia as the maximum when
the operation was performed with great care, and Dr. Henry in like
circumstances, produced 181, whilst I found 187 measures; since that,
as has been related, Dr. Henry has found 200 measures. It is not easy
to account for these differences; I am inclined to the opinion that the
volume of gases is very nearly doubled, but probably rather less than
more. I find the experiments on the rapid combustion of ammonia agree
best with that opinion.
_Decomposition of ammonia by a red heat._--A short time since I
repeated the decomposition of ammonia by passing the gas through a red
hot copper tube. The proportion of azote to hydrogen, due allowance
being made for a minute portion of atmospheric air, was upon the
average of a number of experiments, 26 of the former to 74 of the
latter.
_Decomposition of ammonia by oxymuriatic acid._--I have made several
experiments on this mode of decomposition since the results published
in vol. 1, page 435. It is well known that a solution of oxymuriate
of lime decomposes ammoniacal salts; water and muriatic acid are
produced, azote liberated, and the acid previously combined with the
ammonia is evolved. But this is not all; an excessively pungent gas or
perhaps vapour is produced, exciting sneezing, and inducing catarrh;
the constitution of this vapour is not well understood; it is never
formed, as far as I know, without the presence of both oxymuriatic acid
and ammonia. The results of such mixtures are of course complicated and
likely to be unsatisfactory; it may notwithstanding be useful to relate
some of them.
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