A new system of chemical philosophy, Volume 2, Part 1Dalton, John
Science
A new system of chemical philosophy, Volume 2, Part 1
Dalton, John
Atomic theory; Chemistry, Inorganic
From the above it would seem that the proportions for mutual saturation
must be 10 nitrous oxide with from 7 to 8 parts of ammonia. This
agrees with the deduction in Dr. Henry’s first essay that 13 nitrous
oxide require 10 of ammonia; or that 10 require 7.7: but according to
the theory of volumes 10 would require 6⅔; and Dr. Henry recommends
in his late essay 10 nitrous oxide to 7.7 or 8⅓ parts of ammonia, in
order to secure a small excess of the last, and consequently some
free hydrogen after the explosion. The former of these proportions
would have nearly ⅐ of the residue hydrogen, and the latter nearly ⅕,
supposing the gases pure originally. This gives more hydrogen than I
have ever found; but the azote in my experience nearly agrees with the
doctrine of multiple volumes.
_Decomposition of ammonia by nitrous gas._--About 30 experiments
carefully made on mixtures of nitrous gas and ammoniacal gas gave very
discordant results. At one time 10 parts nitrous gas with 14 ammonia
gave ⅓ of hydrogen in excess, and another time 10 nitrous with 12
ammonia gave excess of hydrogen = ⁹/₂₀; generally 10 parts with 6 or
less gave oxygen, and 10 with 8 or more gave hydrogen in the residue.
_Decomposition of ammonia by oxygen._--The limiting proportions of
oxygen and ammonia which I have fired, are 10 oxygen to 4 ammonia
for the minimum, and 10 oxygen to 22 ammonia for the maximum. When
10 oxygen were fired with 4 ammonia, there were ²⁵/₃₇ of the oxygen
left, and there was a deficiency of azote amounting to ¹/₁₂ of what was
expected from the ammonia, owing no doubt to nitrous acid generated
by the explosion. When 10 oxygen to 1.8, or from that to 2.2 ammonia
are used, there is a surplus of about ¼ or ⅓ of the hydrogen contained
in the ammonia, left in the residue of the gas. When the ammonia is
between 13 and 14 there is usually a trace of oxygen or hydrogen as
it approaches either of these limits. By the theory of volumes, 10
oxygen should saturate 13⅓ of ammoniacal gas. I have not any instance
of hydrogen being left when 14 ammonia were used, though there ought
to be ¹/₂₀ of the whole left; and much smaller quantities than that
are appreciable by well known methods. The azote resulting from the
decomposition of ammonia is usually very nearly ½ the volume of the
ammonia.
On the whole the results from firing ammonia and oxygen gas appear to
me more satisfactory than those obtained from nitrous oxide and nitrous
gas, as they are more simple and less perplexed with any theoretic
views.
It may be proper to remind the reader that when we speak of 10 parts
of one gas uniting with 8, 10, or more, of another in the above and
other cases, it is to be understood of gases _absolutely pure_; not
that we ever obtain them in that state, but approximating as near as we
can to it, we mix given portions of such gases as we can obtain, and
then in our calculations of results deduct for the impurities.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account