A new system of chemical philosophy, Volume 2, Part 1Dalton, John
Science
A new system of chemical philosophy, Volume 2, Part 1
Dalton, John
Atomic theory; Chemistry, Inorganic
It is generally allowed that the great objects of the atomic system
are, 1st to determine the relative weights of the simple elements;
and 2d to determine the _number_, and consequently the weight, of
simple elements that enter into combination to form compound elements.
The greatest _desideratum_ at the present time is the exact relative
weight of the element hydrogen. The small weight of 100 cubic inches
of hydrogen gas, the important modifications of that weight by even
very minute quantities of common air and aqueous vapour, and the
difficulties in ascertaining the proportions of air and vapour in
regard to hydrogen, are circumstances sufficient to make one distrust
results obtained by the most expert and scientific operator. The
specific gravity of hydrogen gas was formerly estimated at ⅒ that of
common air; it descended to ¹/₁₂.₅, which is the ratio we adopted
in the Table at the end of Vol. 1. it is now commonly taken to be
¹/₁₄.₅, and whether it may not in the sequel be found to be ¹/₁₆.₅
is more than any one at present, I believe, has sufficient data to
determine. The other factitious gases have mostly undergone some
material alterations in their specific gravities in the last twenty
years, several of which I have no doubt are improvements; but when we
see these specific gravities extended to the 3rd, 4th, and 5th places
of decimals, it appears to me to require a credit far greater than
any one of us is entitled to. In the mean time, it may be thought a
fortunate circumstance, that the weight of common air has undergone
no change for the last thirty or forty years; 100 cubic inches bring
estimated to weigh 30.5 grains at the temperature of 60°, and pressure
of 30 inches of mercury: (whether this is exclusive of the moisture I
do not recollect.) It is also a fortunate circumstance, (provided it be
correct) that this weight is nearly free from decimal figures. I may
be allowed to add, that according to my experience, the weight of 100
cubic inches of air is more nearly 31 grains than 30.5. I apprehend
these observations are sufficient to shew that something more remains
to be done before we obtain a tolerably correct table of the specific
gravities of gases; the importance of this object can not be too highly
estimated.
The combinations of gases in equal volumes, and in multiple volumes, is
naturally connected with this subject. The cases of this kind, or at
least approximations to them, frequently occur; but no principle has
yet been suggested to account for the phenomena; till that is done I
think we ought to investigate the facts with great care, and not suffer
ourselves to be led to adopt these analogies till some reason can be
discovered for them.
The 2d object of the atomic theory, namely that of investigating the
_number_ of atoms in the respective compounds, appears to me to have
been little understood, even by some who have undertaken to expound the
principles of the theory.
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