A new system of chemical philosophy, Volume 2, Part 1Dalton, John
Science
A new system of chemical philosophy, Volume 2, Part 1
Dalton, John
Atomic theory; Chemistry, Inorganic
When two bodies, A and B, combine in multiple proportions; for
instance, 10 parts of A combine with 7 of B, to form one compound, and
with 14 to form another, we are directed by some authors to take the
smallest combining proportion of one body as representative of the
elementary particle or atom of that body. Now it must be obvious to
any one of common reflection, that such a rule will be more frequently
wrong than right. For, by the above rule, we must consider the first
of the combinations as containing 1 atom of B, and the second as
containing 2 atoms of B, with 1 atom or more of A; whereas it is
equally probable by the same rule, that the compounds may be 2 atoms
of A to 1 of B, and 1 atom of A to 1 of B respectively; for, the
proportions being 10 A to 7 B, (or, which is the same ratio, 20 A to 14
B,) and 10 A to 14 B; it is clear by the rule, that when the numbers
are thus stated, we must consider the former combination as composed
of 2 atoms of A, and the latter of 1 atom of A, united to 1 or more of
B. Thus there would be an _equal_ chance for right or wrong. But it is
possible that 10 of A, and 7 of B, may correspond to 1 atom A, and 2
atoms B; and then 10 of A, and 14 of B, must represent 1 atom A, and 4
atoms B. Thus it appears the rule will be more frequently wrong than
right.
It is necessary not only to consider the combinations of A with B,
but also those of A with C, D, E, &c.; as well as those of B with
C, D, &c., before we can have good reason to be satisfied with our
determinations as to the _number_ of atoms which enter into the various
compounds. Elements formed of azote and oxygen appear to contain
portions of oxygen, as the numbers 1, 2, 3, 4, 5, successively, so
as to make it highly improbable that the combinations can be effected
in any other than one of two ways. But in deciding which of those two
we ought to adopt, we have to examine not only the compositions and
decompositions of the several compounds, of these two elements, but
also compounds which each of them forms with other bodies. I have spent
much time and labour upon these compounds, and upon others of the
primary elements carbone, hydrogen, oxygen, and azote, which appear to
me to be of the greatest importance in the atomic system; but it will
be seen that I am not satisfied on this head, either by my own labour
or that of others, chiefly through the want of an accurate knowledge of
combining proportions.
NEW TABLE OF THE RELATIVE WEIGHTS OF ATOMS.
At the close of the last volume, the weights of several principal
chemical elements or atoms were given; but as several additions and
alterations have been educed from subsequent experience, it has been
judged expedient to present a reformed table of weights.
SIMPLE ELEMENTS.
Public-domain text, read in full here on John Shaqi.
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