A new system of chemical philosophy, Volume 2, Part 1Dalton, John
Science
A new system of chemical philosophy, Volume 2, Part 1
Dalton, John
Atomic theory; Chemistry, Inorganic
Zinc. Oxygen.
1766. Cavendish 100 + 23.3
1785. Lavoisier -- + 19.6
1790-1800. Wenzel and Proust -- + 25
1801. Desorme and Clement -- + 21.7
Davy -- + 21.95
Berzelius -- + 24.4
Gay Lussac -- + 24.4
Thomson -- + 24.42
My own -- + 24
Now if 24 oxy. ∶ 100 zinc ∷ 7 oxy. ∶ 29 zinc, nearly, which is
therefore the weight of an atom of this metal, on the supposition that
the oxide is 1 oxygen and 1 metal; and the atom of oxide = 36.
I formerly estimated the atom of zinc at 56 (VOL. 1, page 260). This
was occasioned by taking the above as the _deutoxide_ instead of the
_protoxide_. By violently heating the oxide of zinc in a close vessel,
Desorme and Clement reduced the oxygen nearly one half, so as to
afford a presumption that an oxide with half the oxygen of the common
one subsisted. Since that time some observations of Berzelius seem to
shew that a suboxide of zinc exists. It does not appear however, that
such oxide is ever found in combination with acids; and, granting the
accuracy of the observations, it is rather to be presumed to be the
semi-oxide, or 1 atom of oxygen and 2 of metal, than the protoxide.
No higher oxidation of zinc than the above has yet been obtained, and
probably does not exist.
15. _Oxides of potassium._
Since writing the articles “potassium and sodium,” in the former
volume, a very important essay relating chiefly to these subjects has
been written by Gay Lussac and Thenard (a copy of which they were so
good as to send me), entitled “Recherches Physico-chimiques, &c.” in
2 VOL.--Many of the most interesting experiments of Davy have been
repeated on a larger scale, and a great number of original ones added;
these ingenious authors endeavour to sum up the evidences for and
against the two hypotheses concerning potassium and sodium, namely,
as to their being metals or hydrurets, and upon the whole incline to
the former, allowing however, that the facts afford great plausibility
to both. One thing they seem to have discovered and established, that
the new bodies or metals admit of various degrees of oxidation, and
of course these products have a claim to be classed amongst oxides in
general though the nature of their bases may still be an object of
dispute.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account