A new system of chemical philosophy, Volume 2, Part 1 — John Shaqi
A new system of chemical philosophy, Volume 2, Part 1Dalton, John
Science
A new system of chemical philosophy, Volume 2, Part 1
Dalton, John
Atomic theory; Chemistry, Inorganic
Gay Lussac and Thenard find a suboxide of sodium in the same way as
that of potassium, and it is probably a compound of soda and sodium:
the remarkable oxidation which produces soda is, I should imagine, the
protoxide or one atom to one, as obtained by placing sodium in contact
with water. A higher oxide is obtained as with potassium, by burning
sodium in oxygen gas with a vivid heat. It resembles the yellow oxide
of potassium in its appearance and properties. The degree of oxidation
varies in the different experiments from 1¼ to 1¾ times the oxygen of
soda. It is probably a combination of the protoxide and deutoxide.
Hence the oxides of sodium may be as under; reckoning the atom of
sodium 21, and soda 28.
Sodium. Oxygen.
Protoxide (Soda) 100 + 33⅓
Intermediate oxide 100 + 50
17. _Oxide of bismuth._
Only one oxide of bismuth is known, and the proportion of its parts has
been gradually approximated by Bergman, Lavoisier, Klaproth, Proust,
and others. Berzelius mentions a purple oxide obtained by exposing
bismuth to the action of the atmosphere; but as no experiments have
been made upon it, we cannot adopt it at present. According to Klaproth
and Proust, 100 bismuth unite with 12 oxygen; but by the more recent
experiments of Mr. J. Davy and Lagerhjelm 100 bismuth take 11.1 or 11.3
oxygen. If we adopt this last, which is doubtless near the truth; we
shall have 11.3 ∶ 100 ∷ 7 ∶ 62 for the weight of the atom of bismuth,
on the supposition that the compound is the protoxide or 1 atom of
metal to 1 of oxygen. My former weight of bismuth was 68 (page 263),
which is clearly too high.
Bismuth is best oxidized by nitric acid. Part of the oxide combines
with the acid and part precipitates in the state of a white powder; if
the whole be gradually heated, the acid is driven off, and at a low red
the oxide remains pure; it is fused into glass and of a red or yellow
colour, according to the heat employed. Bismuth may also be oxidized by
heat in open vessels; yellow fumes arise which may be condensed and are
found to be the oxide.
18. _Oxides of antimony._
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