A new system of chemical philosophy, Volume 2, Part 1Dalton, John
Science
A new system of chemical philosophy, Volume 2, Part 1
Dalton, John
Atomic theory; Chemistry, Inorganic
100 antimony to form the grey oxide. Whether this is the protoxide or
deutoxide may be disputed; and the facts known concerning the other
oxide or oxides will scarcely determine the case: but the proportions
of the muriate and sulphuret of antimony accord much better with the
former supposition. Now if 18 ∶ 100 ∷ 7 ∶ 39, for the weight of the
atom of antimony; I prefer the weight 40, deduced from the sulphuret,
as announced in VOL. 1, page 264.
The oxide which contains 30 on 100 must be 2 atoms of the deutoxide
and 1 of the protoxide united. What Berzelius calls the white oxide or
antimonious acid, may be 1 atom of each oxide united, containing 27
oxygen on the 100. The oxide supposed to contain 36 or 37 oxygen on
100, and which must be considered as the deutoxide, has not been proved
to exist separately. My efforts to procure it have failed as well as
those before mine: by treating muriate of antimony with oxymuriate of
lime I have obtained oxides of 30 on the 100, but never much higher.
Whenever a greater proportion of oxymuriate of lime is added, the smell
of the gas becomes permanent.
Antimony exposed to a red heat in a current of common air or oxygenous
gas takes fire, and white fumes arise formerly called _flowers of
antimony_; this oxide contains 27 or 30 oxygen on 100 metal.
Antimony thrown into red hot nitre is oxidized rapidly; the remaining
powder, washed in water, is found to be a compound of oxide of antimony
and potash. Berzelius calls the oxide the antimonic acid, and the salt
the _antimoniate of potash_. It consists, according to his experience,
of 100 acid and 26.5 potash. A similar salt formed between the
antimonious acid and potash is constituted of 100 acid and 30.5 potash.
19. _Oxide of tellurium._
We are chiefly indebted to Berzelius for the proportions in which
tellurium combines. He finds 100 tellurium unite to 24.8 oxygen. Also
that 201.5 tellurate of lead gave 157 sulphate of lead. This last
contains 116 oxide of lead, which must therefore have combined with
85.5 of the oxide of tellurium. Hence 97 oxide of lead would combine
with 71.5 oxide of tellurium = 57½ tellurium + 14 oxygen. Whether
this oxide of tellurium is the protoxide or deutoxide, is somewhat
uncertain. The atom of tellurium will weigh 57½ in the latter case,
but only 28 or 29 in the former. The analogy of the oxide to acids
favours the notion of a deutoxide; but the facility with which the
tellurium is volatilized by hydrogen is in favour of the lighter atom.
The oxide is a white powder; it is produced by dissolving the metal in
nitro-muriatic acid and precipitating by an alkali.
20. _Oxides of arsenic._
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account