A new system of chemical philosophy, Volume 2, Part 1Dalton, John
Science
A new system of chemical philosophy, Volume 2, Part 1
Dalton, John
Atomic theory; Chemistry, Inorganic
If to 24 parts of lime dissolved in water we put 98 parts of dry
arsenic acid, the compound remains in solution, and is perfectly
neutral to the colour test, but so that the addition of a small
quantity of either ingredient disturbs the neutrality. If to this
solution 24 parts of lime dissolved in water be added, the compound
remains a limpid solution, but is very limy to the test. If to this
we put in like manner, 24 parts more of lime, the whole compound is
thrown down, and yields, when dried, 170 parts of arseniate of lime,
the liquid being now free from both elements. Here we see first, two
atoms of the deutoxide, neutralized by two atoms of base, namely, 1 of
arsenic oxide, and 1 of lime; but (second), when one atom more of lime
is added, an union of 2 deutoxide, and 3 of base is effected, which of
course is an alkaline salt; when (third) more of lime is added, the 2
deutoxide and the 1 protoxide each attach 1 of lime, and form a still
more alkaline salt, which being insoluble, is wholly thrown down, most
probably in a compound state of 98 parts arsenic acid, combined with 72
parts lime.
In like manner, I find that 42 parts of potash, 28 of soda, and 12 of
ammonia, severally neutralize 98 parts of arsenic acid.
1st. 24 lime + 32.7 arsenic acid = insoluble arseniate
2d. -- + 49 ------------ = soluble arseniate
3d. -- + 98 ------------ = neutral arseniate
It is a remarkable fact, that when neutral arseniate of potash
and nitrate of lead are mixed together to mutual saturation, the
precipitate is found to consist chiefly of arsenic acid and oxide of
lead, in proportion of 1 of acid to two of oxide, (that is, 98 ∶ 194,
or 100 ∶ 198); which does not differ much from the determination of
Berzelius.
I find however, only one fourth of the nitric acid in the residuary
liquid in a free state; which leads me to suspect that the precipitate
is a compound of subnitrate and arseniate of lead, in which the arsenic
acid and lead are in due proportion, or 98 acid, to 97 oxide. This
consideration may be properly resumed hereafter.
Hence we conclude, the atom of arsenic weighs 21 (and not 42, as at
page 264, VOL. 1), that of the protoxide of common white arsenic,
28; and that of arsenic acid = 98, being a compound of 2 atoms of
deutoxide, and 1 of protoxide. Or,
100 Arsenic + 33.3 oxygen = 133.3 protoxide
-- + 55.5 ---- = 155.5 arsenic acid
21. _Oxides of cobalt._
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