A new system of chemical philosophy, Volume 2, Part 1Dalton, John
Science
A new system of chemical philosophy, Volume 2, Part 1
Dalton, John
Atomic theory; Chemistry, Inorganic
When quadrisulphuret of lime is treated with an alkaline carbonate, a
reciprocal change takes place; the carbonic acid takes the lime, and
the alkali the sulphur, leaving however 1 atom of sulphur with the
carbonate which precipitates. Hence a sulphuretted carbonate of lime is
obtained and a trisulphuret of the alkali. The sulphur burns off from
the carbonate below a red heat and leaves 75 per cent. of carbonate of
lime; this affords an excellent analysis of quadrisulphuret of lime as
far as lime is the object. Thus 540 of the above 1.056 quadrisulphuret
took 100 test carbonate of potash (1.25), and gave a precipitate of
29 grains, which burned blue and left 22 grains = 12 lime, and 10
acid; but if 540 ∶ 12 ∷ 100 ∶ 2.2, as above determined synthetically:
moreover, 12 lime, 10 acid, and 7 sulphur, are as 24 lime, 20 acid,
and 14 sulphur; the composition of an atom of sulphuretted carbonate
of lime, which is analogous to the sulphuretted sulphite of lime, as
found above.
When quadrisulphuret of lime is treated with as much sulphuric acid
as is sufficient for the lime, the sulphur is in part precipitated,
but it is in union with the sulphate of lime, or at least they are
not separable by mechanical means. This compound is sold in the shops
under the name of precipitated sulphur. It is about one half sulphate
of lime, and the other half sulphur. The nitric and muriatic acids
precipitate the sulphur partially from quadrisulphuret, but the sulphur
assumes a viscid form and exhales sulphuretted hydrogen, and the
proportion of the elements of quadrisulphuret are not easily obtained
by any of these acids.
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