A new system of chemical philosophy, Volume 2, Part 1Dalton, John
Science
A new system of chemical philosophy, Volume 2, Part 1
Dalton, John
Atomic theory; Chemistry, Inorganic
The mutual action of quadrisulphuret of lime, and the metallic salts
is curious and interesting; for instance, with nitrate of lead. Let
a solution of nitrate of lead, containing 97 oxide, be treated with
a solution of quadrisulphuret of lime by degrees, as long as a black
precipitate appears, marking the exact point of saturation; this will
be found when 36 parts of lime have entered, and 84 of sulphur; the
sulphuret of lead will fall, and when dried will weigh 145 parts,
and contain 90 lead, and 55 sulphur; that is, 1 atom of lead, and 4
of sulphur, and is consequently a quadrisulphuret of lead. The liquid
remains clear and colourless, and contains the nitric acid, lime,
oxygen of the lead, and ⅓ of the sulphur; each atom of nitric acid
combines with one of lime, which retains one of the 4 atoms of sulphur,
forming a sulphuretted nitrate of lime, consisting of 45 acid, 24 lime,
and 14 sulphur; the 7 parts of oxygen unite with 7 of sulphur to form
sulphurous acid, which require 12 parts of lime to saturate them and
7 of sulphur, forming a sulphuretted sulphite of lime: hence we see
that 28 parts of sulphur remain in the liquor, and the rest (56) unite
with the lead. If now we add gradually more nitrate of lead, a silvery
white precipitate appears, increasing till half the original quantity
is added, and then the liquid is saturated. This white precipitate is
sulphuretted sulphite of lead; when heated it soon grows black and
loses 15 or 20 per cent., being then a protosulphuret of lead. The
liquid now contains sulphuretted nitrate and simple nitrate of lime;
nitrate of lead has no effect, but nitrate of mercury precipitates a
black sulphuret.
Quadrisulphuret of lime saturated with oxygen, as has been observed,
contains sulphuretted sulphite of lime in solution, and deposits
sulphur: the liquid treated with nitrate of lead, gives as above the
white, silvery sulphuretted sulphite of lead as a precipitate, and
holds nitrate of lime in solution.
_Hydrosulphuret of lime._ This compound may be formed by passing
sulphuretted hydrogen into lime water; the water assumes a brownish
colour, but the point of saturation is not easily found, as the lime
water is not neutralized so as to shew by the colour test, and water
of itself absorbs above twice its volume of the gas. By means of a
neutral solution of nitrate of lead it may be found that 1000 lime
water in volume, require about 600 sulphuretted hydrogen, because then
a mutual saturation is observed by double affinity; that is, sulphuret
of lead and neutral nitrate of lime are formed; but otherwise the
liquid remaining is either acid or alkaline. Hydrosulphuret of lime,
as well as the other hydrosulphurets, has a peculiar bitter taste. It
forms a useful reagent in regard to metals, but is apt to be spoiled by
keeping, owing to the acquisition of oxygen.
2. _Sulphuret of magnesia._
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account