A new system of chemical philosophy, Volume 2, Part 1Dalton, John
Science
A new system of chemical philosophy, Volume 2, Part 1
Dalton, John
Atomic theory; Chemistry, Inorganic
Such however is the repulsion of oxygen to oxygen that we rarely
find three atoms of it retained by a single atom of any kind; and
there are not many instances of metals capable of holding two atoms
of oxygen. Various modifications of the proportions of metals and
oxygen arise from the combinations of the oxides themselves one with
another and with oxygen, so as to lead some to imagine that an atom of
metal in some instances combines with 3, 4, or more of oxygen. This
is altogether improbable: It is much more simple to suppose that one
atom of oxygen connects two or more atoms of protoxide, 1 of protoxide
unites to 1 or more of deutoxide, &c. These intermediate oxides are in
few if any instances found to combine with acids like the other two
oxides.
There is no reason that I am acquainted with for disbelieving that
oxygen combined with a metal is still repulsive of oxygen, and that by
the same law as particles of an elastic fluid; that is, the repulsion
is inversely as the distance of the centres of the atoms. Hence it
may be demonstrated that it requires twice the strength of affinity
to form a deutoxide as a protoxide, three times the strength to
form a tritoxide as a protoxide, &c. On this account it is, in all
probability, that deutoxides are not numerous, and tritoxides are
rarely if ever found.
The quantity of oxygen that combines with any metal to form an oxide
may be investigated by several methods.
1st. By combustion; a given weight of the metal may be burned and the
oxide produced may be collected and weighed; when the increase by
combustion will appear.
2. By solution in an acid and precipitation by an earth or alkali; in
this case a given weight of the metal is dissolved and precipitated;
the precipitate collected and sufficiently dried shews the increase by
oxygen.
3. By transferring the oxygen from an oxide to another metal; in this
case the metal in question is usually immersed in a saline solution of
the other metal; this latter metal gives up its oxygen to the former
and is itself reformed or _revived_ as it is termed.
4. By determining the proportion of hydrogen gas evolved during the
solution of a given weight of metal; then allowing half of that volume
for its equivalent of oxygenous gas, the weight of it shews the oxygen
united to the metal; it being now well understood that water furnishes
the two elements of hydrogen and oxygen in such case.
5. The higher oxides are conveniently determined by the application of
the solution of oxymuriate of lime to the lower oxides in solution.
6. The quantity of oxygen in several oxides may be found from the
quantity of nitrous gas evolved during the solution of a given weight
of metal in nitric acid.
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