A new system of chemical philosophy, Volume 2, Part 1Dalton, John
Science
A new system of chemical philosophy, Volume 2, Part 1
Dalton, John
Atomic theory; Chemistry, Inorganic
Sir H. Davy and Gay Lussac have investigated several compounds of
phosphorus, particularly with muriatic and oxymuriatic acids, and with
the new metals potassium and sodium, which I shall have to notice in
their proper places.
Other authors have written on phosphurets besides those I have
mentioned, but they do not require to be particularly distinguished
in this enumeration. We shall therefore proceed to describe the
phosphurets more particularly.
1. _Phosphuret of hydrogen._
From recent experiments which I have made on phosphuretted hydrogen
gas, I find the account already given (VOL. 1. page 456) is deficient,
and in several respects inaccurate; I shall therefore substitute the
following, as more perfect and correct.
Phosphuretted hydrogen may be obtained nearly pure, by the methods
recommended by Dr. Thomson. Phosphuret of lime that has been carefully
secluded from the atmosphere, may be put into a small phial filled
with water, acidulated by muriatic acid; into this a cork with a bent
tube must be immediately put under water, so that the phial and tube
are both full of water; gas soon begins to appear, which rising to
the top of the phial, expels a corresponding portion of water, and in
due time the gas itself comes over and may be received as usual: if
the phial in which the gas is generated be warmed to 140 or 150°, the
gas is given out more readily. A half ounce phial with 20 grains of
phosphuret in small lumps, will produce 3 or 4 cubic inches of gas.
If the phosphuret of lime has been previously exposed for a few hours
to the atmosphere, the gas is more abundant, but consists chiefly of
hydrogen, mixed with a little phosphuretted hydrogen.
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