A new system of chemical philosophy, Volume 2, Part 1Dalton, John
Science
A new system of chemical philosophy, Volume 2, Part 1
Dalton, John
Atomic theory; Chemistry, Inorganic
Pure phosphuretted hydrogen is distinguished by the following
properties: 1. It explodes when coming into the atmosphere in bubbles,
and a white ring of smoke subsequently ascends: 2. It is unfit for
respiration, and for supporting combustion: 3. Its specific gravity
is 1.1 nearly, that of atmospheric air being unity: 4. Water absorbs
fully ⅛ of its bulk of this gas, which is expelled again by ebullition
or by agitation with other gases, but not without some loss: 5. A
small portion being electrified for some time, deposits abundance of
phosphorus, and expands from one volume to 1⅓ nearly, which is found to
be pure hydrogen: 6. Liquid oxymuriate of lime absorbs phosphuretted
hydrogen, converting it into phosphoric acid and water, and leaves any
free hydrogen that may be present; hence we are enabled to ascertain
the proportion of free hydrogen in any such mixture, an important
point as far as regards this gas: 7. One volume of pure phosphuretted
hydrogen, requires two volumes of oxygen for its complete combustion by
an electric spark, in Volta’s eudiometer; (the gases must be previously
mixed in a tube not more than ³/₁₀ of an inch in diameter, to prevent
an explosion in the act of mixing, after which they may safely be
transferred into any other vessel); the result of the combustion is
phosphoric acid and water: 8. One volume of phosphuretted hydrogen,
mixed with from 2 to 6 volumes of nitrous gas, may be exploded by
electricity in Volta’s eudiometer; or it may be exploded by sending
up a bubble of oxygen, without electricity; in like manner, may the
mixtures of phosphuretted hydrogen and oxygen be exploded by a bubble
of nitrous gas: 9. One volume of phosphuretted hydrogen, mixed with
4, less or more, of nitrous oxide, is also explosive by electricity,
but the mixture undergoes no change without electricity, at least in
a day: 10. Mixtures of phosphuretted hydrogen and nitrous gas have a
slow chemical action, by which in from 1 to 12 hours, the phosphuretted
hydrogen is burnt and the nitrous gas decomposed into nitrous oxide and
azotic gas: 11. According to Sir H. Davy and Dr. Thomson, phosphuretted
hydrogen gas being heated along with sulphur in a dry tube, the gas is
decomposed and a new gas, sulphuretted hydrogen, is formed, and the
phosphorus unites with the sulphur. Davy says the gas is doubled in
volume by this operation; but Thomson says it remains the same; some
doubt therefore exists respecting this fact: 12. When phosphuretted
hydrogen gas is let up to oxymuriatic acid gas, a quick combustion with
a yellow flame is observed, and the result varies according to the
proportions: when one volume phosphuretted hydrogen is put to 3 or 4
of acid gas, both of the gases disappear, and muriatic and phosphoric
acids are produced.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account