A new system of chemical philosophy, Volume 2, Part 1Dalton, John
Science
A new system of chemical philosophy, Volume 2, Part 1
Dalton, John
Atomic theory; Chemistry, Inorganic
In the present instance, however, I have been more circumstantial;
after repeatedly agitating water with pure azotic gas, so as to
saturate it and expel the oxygen, I then put in 110 grain measures
of phosphuretted hydrogen composed of 100 pure gas, 5 hydrogen, and
5 azotic gas or rather atmospheric air. After due agitation, all was
absorbed but 35; this was mixed with a known portion of oxygen and
exploded; the diminution was 19 measures; the oxygen remaining was
determined by hydrogen; from which it appeared that 10 combustible
gas had taken 9 oxygen. Now 10 being ²/₇ of 35, we may consider the
water as ²/₇ impregnated with the phosphuretted hydrogen, and ⁵/₇ with
azote; but as there were 105 combustible gas and only 10 left, 95 must
have entered the water and caused it to be ²/⁷ charged with the gas;
whence we may infer that 332 gas would have been a full charge for 2700
water, which is almost exactly ⅛, as stated above. Other experiments
gave corresponding results. On admitting 51 azotic gas to the water,
and agitating it a good deal for 4 or 5 minutes, there came out 51
measures or the same volume: this was found in the same way to consist
of 43 azote and 8 combustible, which took 10 oxygen. Again 51 azote
was agitated in the water, and there came out 51, of which 5 + were
combustible and took 9 oxygen. After this the bottle of water was put
into a pan of water which was raised to the boiling heat, a bent tube
filled with water being adapted to the water bottle, and having its end
immersed in water: by this operation gas was expelled from the water,
and caught in the neck of the bottle; when it amounted to 22 grain
measures it was transferred and was found to consist of 17 azote + 5 +
combustible, which took 10 oxygen. By these experiments we see that the
gas is expelled again from the water, both by ebullition and by other
gases, nearly the same in quality, but much diminished in quantity,
the reason of which is not very obvious. The liquid now required 30
measures of oxymuriate of lime, equivalent to 100 measures of oxygen,
before it was saturated; that is, there appeared to be 50 phosphuretted
hydrogen remaining in the water. Adding a little lime water threw down
a very sensible quantity of phosphate of lime.
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