A new system of chemical philosophy, Volume 2, Part 1Dalton, John
Science
A new system of chemical philosophy, Volume 2, Part 1
Dalton, John
Atomic theory; Chemistry, Inorganic
As these properties differ in many respects from those hitherto
assigned to this gas, it will be necessary to enlarge upon them. The
sp. gr. of this gas has already been adverted to, (VOL. 1.), and its
great variation from .3 to .85; more recently Dr. Thomson finds it
about .9. In all these instances it was, I have no doubt, contaminated
with less or more of hydrogen; at least it was so in my own instance;
for, I have the proportion of oxygen which it required for its complete
combustion, both before and after it was weighed. It was what I then
thought pure gas: that is, 100 volumes required nearly 150 of oxygen;
but I am now convinced that gas of this description contains ⅓ of its
volume of free hydrogen; hence the correction of the sp. gravity. Davy
estimates the sp. gr. of the gas which he denominates _hydrophosphoric_
at .87 or 12 times that of hydrogen; this gas, as will appear from this
and other properties, is in all probability phosphuretted hydrogen gas,
nearly pure.
The absorption of this gas by water, has been stated variously. In 1799
M. Raymond found that water absorbs rather less than ¼ of its volume of
this gas: in 1802, Dr. Henry rates its absorption at ¹/₄₇ only; in 1810
I found it ¹/₂₇; in 1812, Davy found it (hydrophosphoric gas) to be ⅛;
in 1816, Dr. Thomson found it to be ¹/₄₇; I now estimate it as stated
above at ⅛. These enormous differences may be partly accounted for by
varieties in the gas; and partly from the theory of the absorption
not being understood; but these are scarcely sufficient excuses in
all the cases. I find that my early experiments on the absorption of
phosphuretted hydrogen by water, were made prior to the discovery of
the method of analysing the gas by electric combustion; consequently
they were deficient in regard to the quality of the gas, both before
and after agitation; the best gas that ever I had, was such as took
150 oxygen per cent. for its combustion, exclusive of any common air;
and it was often such as to require considerably less. The bottle
which I used for the purpose in 1810 contains 2700 grains of water; at
first I charged water with hydrogen: into this 120 grain measures of
phosphuretted hydrogen were put, and the whole well agitated: there
were left 98 measures;--this proved that the gas was more absorbable
than hydrogen: into the same water were put 98 more phosphuretted
hydrogen and agitated; out, 80; this confirmed the proof: Into the same
water were put 97 hydrogen and agitated well; out 105: This shewed
that the hydrogen had expelled a part of the gas again, and was less
absorbable of the two. As the phenomena were much the same as if oxygen
had been used instead of phosphuretted hydrogen, it was concluded to
have the same absorbability.
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