A new system of chemical philosophy, Volume 2, Part 1Dalton, John
Science
A new system of chemical philosophy, Volume 2, Part 1
Dalton, John
Atomic theory; Chemistry, Inorganic
M. Pelletier heated together in a crucible, half an ounce of pure gold,
one ounce of phosphoric glass and ⅛ of an ounce of powdered charcoal,
the heat was raised sufficiently to fuse the gold. Phosphoric fumes
arose, but the whole of the phosphorus was not dissipated. The gold
remaining was whiter than natural, and brittle under the hammer.
Exposed to a very high heat it lost ¹/₂₄ of its weight, and resumed the
ordinary characters of gold.
The same chemist heated 100 grains of pure gold in filings to a bright
red; he then projected small fragments of phosphorus amongst the gold
successively till after it had entered into fusion. The gold preserved
its colour, but became brittle under the hammer and granular in the
fracture; it had increased 4 in weight.
Mr. Edmund Davy, by heating in a tube deprived of air, finely divided
gold and phosphorus, effected a combination of them. It had a grey
colour and metallic lustre. The heat of a spirit lamp was sufficient
to decompose it. It contained about 14 per cent. of phosphorus.
(Davy’s Chemistry, page 448--An. 1812).
Oberkampf and Thomson have successively observed the precipitation
occasioned by water impregnated with phosphuretted hydrogen, in
solutions of muriate of gold. The former of these has some interesting
remarks on the phenomena. When a current of this gas is passed through
a dilute solution of muriate of gold for a time, and then suddenly
discontinued, the solution becomes brown and passes soon to a fine deep
purple. A yellowish brown precipitate is obtained, which is metallic
gold, and the liquid, now become yellow again, contains muriate of gold
and phosphoric acid. The experiment may be continued with the like
results. But if the liquid be saturated with gas before any precipitate
is suffered to subside, a black powder is obtained which does not
seem to contain any metallic gold, and the liquor ceases to have any
colour. This black powder is the phosphuret of gold; exposed to heat it
inflames and leaves metallic gold, but its elements are not separable
by mechanical means. (An. de Chimie, 80--146, for 1811).
Water impregnated with the gas was found to have like effects as the
gas itself. Whence Oberkampf concludes that as long as an excess of
gold remains in solution, the phosphuretted hydrogen precipitates the
metal only; but when the gas is in excess, the phosphorus leaves the
hydrogen and unites with the precipitated gold.
Public-domain text, read in full here on John Shaqi.
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