A new system of chemical philosophy, Volume 2, Part 1Dalton, John
Science
A new system of chemical philosophy, Volume 2, Part 1
Dalton, John
Atomic theory; Chemistry, Inorganic
I should rather suppose that the precipitation of the gold may be,
in part at least, owing to the _free_ hydrogen which we now know
accompanies the phosphuretted hydrogen largely, in the manner in which
this gas was formerly procured; however that may be, I find that water,
impregnated with the purest phosphuretted hydrogen, has the property
of precipitating the black phosphuret of gold from the muriate of
that metal, in such manner as to effect complete mutual saturation,
leaving nothing in the liquid but the muriatic acid. Let a solution
containing a known quantity of gold be gradually dropped into water,
containing a known quantity of phosphuretted hydrogen, as long as any
black precipitate is formed. The point of saturation will be found when
60 parts by weight of gold have united to 9 of phosphorus, nearly; or
when one atom of gold has united to one of phosphorus. Hence it may be
concluded that 100 grains of the phosphuret of gold contain 13 or 14
of phosphorus, which agrees very nearly with the results of Mr. Edmund
Davy abovementioned.
8. _Phosphuret of platina._
M. Pelletier succeeded in combining platina with phosphorus by the same
methods as with gold. By projecting phosphorus on grains of platina
heated to a strong red, the latter acquired an increase of weight of
18 on the hundred; but this was probably an excess, as some vitreous
phosphoric acid was found mixed with the mass.
In the Philos. Magazine, VOL. 40, Mr. E. Davy has related some
experiments made with a view to combine platina and phosphorus; he
effected it by heating platina and phosphorus together in an exhausted
tube; the union commenced below a red heat and was attended with vivid
ignition and flame. The compound was of a blueish grey colour and
consisted of 82½ platina and 17½ phosphorus according to his estimate.
Also by heating the ammonia-muriate of platina with ⅔ of its weight of
phosphorus in a retort over mercury, muriatic gas was liberated, and
muriate of ammonia and phosphorus were sublimed, but there remained at
dull red heat an iron black or dark grey mass at the bottom, of the sp.
gr. 5.28. It was estimated to consist of 70 platina and 30 phosphorus;
but I doubt whether it could consist of these two elements only.
Phosphuretted hydrogen water scarcely has any effect on muriate of
platina. After some time a very light flocculent matter appears, as
Dr. Thomson has observed; but this seems to me to be nothing but a
slight precipitation of phosphorus alone; I apprehend the gas unites
with the platina, but the compound remains in solution somewhat in the
same manner as platina and sulphuretted hydrogen. The platina may be
precipitated from the clear liquid by muriate of tin, much the same in
appearance as if no phosphuretted hydrogen were present.
9. _Phosphuret of silver._
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