A Practical Handbook on the Distillation of Alcohol from Farm ProductsWright, F. B. (Frederic B.)
Science
A Practical Handbook on the Distillation of Alcohol from Farm Products
Wright, F. B. (Frederic B.)
Alcohol; Alcohol, Denatured
In Fig. 34 is shown a form of Gillaume still designed to distill all
sorts of liquids whether thin or thick. The wash is supplied from an
overhead tank to a regulating tank _K_ from which a pipe _k_ leads to a
regulating tap _m_. The wash re-ascends into the wash heater _B_ and when
heated descends by pipe _F_ into the uppermost compartments of the column
_A_. The vapor passes to the condenser _B_, by a pipe _H_, and the spent
wash is discharged by a siphon _C_. In addition to the parts above
referred to, _a_ designates entrance of wash into heater, _b_ exhaust
test tube, _d_ steam entrance tap _G_ alcohol test glass, _G¥_ exhaust
test glass, _o_ valve for regulating strength of spirit, _O_ steam
regulator, _p_ water entrance tap, _r_ exit tap, and _D_ the spent wash
extractor.
The Gillaume apparatus is particularly valuable for the production of
industrial or agricultural alcohol. It is claimed that it is easily
understood and operated even by unskilled labor, while it produces a
large proportion of alcohol of a high strength.
A view of a complete apparatus on a large scale is shown in the Fig. 40
in the chapter on rectification.
CHAPTER V.
RECTIFICATION.
The product of the distillation of alcoholic liquors, which is termed
_low wine_, does not usually contain alcohol in sufficient quantity to
admit of its being employed for direct consumption. Besides this it
always contains substances which have the property of distilling over
with the spirit, although their boiling points, when in the pure state,
are much higher than that of alcohol. These are all classed under the
generic title of _fusel-oil_; owing to their very disagreeable taste and
smell, their presence in spirit is extremely objectionable. In order to
remove them, the rough products of distillation are submitted to a
further process of concentration and purification. Besides fusel-oil,
they contain other substances, such as aldehyde, various ethers, etc.,
the boiling points of which are lower than that of alcohol; these must
also be removed, as they impart to the spirit a fiery taste. The whole
process is termed _rectification_, and is carried on in a distillatory
apparatus.
As before stated, the wash as discharged into the still consists of
alcohol mixed with water and a variety of impurities from which the
alcohol must be separated. In order that the process may be better
understood we will assume that a mixture of pure alcohol and water is to
be operated on in place of the wash as above referred to. Distillation in
this case is intended to deprive the water of its alcohol, the operation
theoretically leaving water in one chamber and alcohol in another. This
is accomplished by reason of the differences in the boiling points of
water and alcohol. The alcohol vaporizes at a lower degree (173∞ F.) than
water (212∞ F.) Thus the liquid at the end of the operation has been
divided into two parts or _fractions_.
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