A Practical Handbook on the Distillation of Alcohol from Farm ProductsWright, F. B. (Frederic B.)
Science
A Practical Handbook on the Distillation of Alcohol from Farm Products
Wright, F. B. (Frederic B.)
Alcohol; Alcohol, Denatured
This test is made in a glass of special shape broad at the bottom and
narrowing at the top in order to concentrate the aroma of the product.
Ordinary brandies are tested undiluted. Commercial alcohols, of about 95
degrees must be diluted with water to a maximum of 30 degrees. Otherwise
the burning tang of the alcohol would preclude any delicacy of perception
and allow impurities to pass unnoticed.
The operation is begun by examination by sense of smell. The glass is
half filled with the liquid diluted with one half of pure water. The
glass is covered with one hand and shaken violently for a few seconds.
Immediately upon uncovering it, the quality of the alcoholic vapors may
be ascertained by their odor.
For the examination by sense of taste, the operator rinses his mouth for
a moment with the liquid itself. The taste of ethyl alcohol is fairly
transient;--it disappears quickly allowing the taste of the accompanying
foreign matter to be perceived almost immediately afterward. With a
little practice this test enables one to distinguish by their flavor the
primal origin of alcohols and to judge of their purity. Some
professionals succeed by training in arriving at high degree of skill in
the art of tasting alcohol as it should be done.
In order to determine the purity of alcohol there are besides chemical
tests used by the trade. These tests, which consist in characterizing and
measuring separately the impurities which alcohol may contain, such as
acids, ethers, aldehydes, bases, etc., belong exclusively to analytical
chemistry; they are extremely delicate and complicated. We will not
venture to touch upon them here.
One of the simplest tests for purity is that of Barbet. This is based
upon the time taken to discolor a solution of permanganate of potash
under the action of the tested alcohol. It is not only very rapid but in
general more practical than other tests. It allows the aggregate of the
impurities contained in an alcohol to be ascertained in a single
operation.
The permanganate solution used is very weak (0. gr. 200 of salt), and of
a violet-red color. The technique of the proceeding is as follows: 50
cubic centimeters of the alcohol to be tested are placed in a glass
vessel the temperature of which is maintained at 64.40∞F. 2 cubic
centimeters of the permanganate solution are abruptly added and the time
noted to within a second. Discoloration is awaited and as soon as it
takes place the time is again noted. The total discoloration of the
permanganate is not very marked and passes through intermediate stages;
therefore it is preferable not to await complete discoloration but to
stop at a pale salmon tint, which tint may be comparatively fixed by a
sample of colored liquid (say a solution of fuchsine and chromate of
potash).
The comparative times of discoloration obtained by M. Barbet with various
commercial alcohols, are as follows:
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