A Practical Manual of the Collodion Process, Giving in Detail a Method For Producing Positive and Negative Pictures on Glass and Paper.Humphrey, S. D. (Samuel Dwight)
Science
A Practical Manual of the Collodion Process, Giving in Detail a Method For Producing Positive and Negative Pictures on Glass and Paper.
Humphrey, S. D. (Samuel Dwight)
Ambrotype; Photography
_Conversion of Sulphuret of Silver into Metallic Silver._--The black
sulphuret of silver may be reduced to the state of metal by roasting and
subsequent fusion with carbonate of soda; but it is more convenient, in
operating on a small scale, to proceed in the following manner:--first
convert the sulphuret into nitrate of silver, by boiling with nitric acid
diluted with two parts of water; when all evolution of red fumes has
ceased, the liquid may be diluted, allowed to cool, and filtered from
the insoluble portion, which consists principally of sulphur, but also
contains a mixture of chloride and sulphuret of silver, unless the nitric
acid employed was free from chlorine; this precipitate may be heated in
order to volatilize the sulphur, and then digested with hyposulphite of
soda, or added to the hypo bath.
The solution of nitrate of silver obtained by dissolving sulphuret of
silver is always strongly acid with nitric acid, and also contains
_sulphate_ of silver. It may be crystallized by evaporation; but unless
the quantity of material operated on is large, it will be better to
precipitate the silver in the form of chloride, by adding common salt, as
already recommended.
* * * * *
On the Use of Test Papers.
[Sidenote: ON THE USE OF TEST PAPERS.]
The nature of the coloring matter which is employed in the preparation of
litmus-paper has already been described at page 98.
In testing for the alkalies and basic oxides generally, the blue
litmus-paper which has been reddened by an acid may be used, or, in place
of it, the turmeric paper. Turmeric is a yellow vegetable substance which
possesses the property of becoming brown when treated with an alkali;
it is however decidedly less sensitive than the reddened litmus, and is
scarcely affected by the weaker bases, such as oxide of silver.
In using test papers observe the following precautions:--they should be
kept in a dark place, and protected from the action of the air, or they
soon become purple from carbonic acid, always present in the atmosphere in
small quantity. By immersion in water containing about one drop of liquor
potassæ in four ounces, the blue color is restored.
Test-papers prepared with porous paper show the red color better than
those upon glazed or strongly sized paper. If the quantity of acid present
however is small, it is not sufficient in any case simply to dip the paper
in the liquid; a small strip should be thrown in, and allowed to remain
for ten minutes or a quarter of an hour.
If the paper, on immersion, assumes a _wine-red_ or purple tint, in place
of a decided red, it is probably caused by carbonic aid gas: in that case
the blue color returns when the paper is washed and held to the fire.
Blue litmus-papers may be changed to the red papers used for alkalies by
soaking in water acidified with sulphuric acid, one drop to half a pint.
* * * * *
The Salting and Albumenizing Paper.
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