A Practical Manual of the Collodion Process, Giving in Detail a Method For Producing Positive and Negative Pictures on Glass and Paper.Humphrey, S. D. (Samuel Dwight)
Science
A Practical Manual of the Collodion Process, Giving in Detail a Method For Producing Positive and Negative Pictures on Glass and Paper.
Humphrey, S. D. (Samuel Dwight)
Ambrotype; Photography
I will here remark that, since the first edition, I have had occasion
to use large quantities of soluble cotton, and have found that if it be
kept in an atmosphere of alcohol and ether, its solubility is somewhat
improved: that is, in the case of its not being used immediately after
its preparation. This is easily kept, by dropping a few drops of ether or
alcohol into the bottle containing it, and then sealing close until wanted
for use. In the event of the water being displaced by alcohol, it is not
necessary to thoroughly dry it, but put in a _perfectly close_ bottle to
keep.
_Remarks._--There are a few precautions necessary to be observed in the
preparation of soluble cotton. I should select a fine clear day, if time
is no object; nevertheless I have made a good article in a moderately
dense atmosphere. Sulphuric acid has a powerful affinity for hydrogen,
consequently, in damp weather, it is more or less reduced by the moisture
in the air.
It is advisable to prepare the nitro-sulphuric acid mixture on a roof,
or between two doors or windows, where there is a good current of air,
in order to prevent the inhalation of white vapors which arise, and are
very poisonous to the lungs. As a preventive, in case of inhaling these
vapors, I apply the fumes of aqua-ammonia. It is best for every one to
have six or eight ounces of this always at hand; it neutralizes all acid
that maybe spattered on the clothes, prevents its destructive powers, and
restores the color.
Yellow vapors sometimes appear when putting the cotton in contact with the
solution: this arises from its not being wet; and when they do appear, the
cotton where they are should be quickly put under the liquid and kneaded
rapidly, which will prevent a continuance of these vapors. I have had them
appear, and used the cotton, and could not observe that any bad effect had
been produced.
The temperature is worthy the attention of the operator: if it be low,
as in winter, and the cotton be left in the nitro-sulphuric mixture for
fifteen or twenty minutes, the whole becomes a thick, stiff mass, bedded
together, and has not had proper action, giving a bad article. A good
temperature is about 140° Fahr. for the last of the time the cotton is
in the mixture. This is not always convenient; so the operator will be
governed by circumstances, taking his chance of having a good article. In
some cases I have heated a _thick_ iron plate, at a moderate temperature,
placing the mortar upon it, and thus aided in regulating the temperature.
This is the most convenient method I have employed.
It has been thought advisable to publish in full the account of Edw.
Ash Hadow's experiments and investigations upon the subject of soluble
cotton. The following is an account of them as it appeared in _Humphrey's
Journal_, vol. VI. p. 12:--
Public-domain text, read in full here on John Shaqi.
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