A Practical Manual of the Collodion Process, Giving in Detail a Method For Producing Positive and Negative Pictures on Glass and Paper.Humphrey, S. D. (Samuel Dwight)
Science
A Practical Manual of the Collodion Process, Giving in Detail a Method For Producing Positive and Negative Pictures on Glass and Paper.
Humphrey, S. D. (Samuel Dwight)
Ambrotype; Photography
Common salt exists abundantly in nature, both in the form of solid
rock-salt and dissolved in the waters of the ocean.
_Properties of the pure Salt._--Fusible without decomposition at low
redness, but sublimes at higher temperatures; the melted salt concretes
into a hard white mass on cooling. Nearly insoluble in absolute alcohol,
but dissolves in minute quantity in rectified spirit. Soluble in three
parts of water, both hot and cold. Crystallizes in cubes, which are
anhydrous.
_Impurities of Common Salt._--Table salt often contains large quantities
of the chlorides of magnesium and calcium, which, being deliquescent,
produce a dampness by absorption of atmospheric moisture: sulphate of
soda is also commonly present. The salt may be purified by repeated
recrystallization, but it is more simple to prepare the pure compound
_directly_, by neutralizing hydrochloric acid with carbonate of soda.
Chloride of Silver. (_See_ Silver, Chloride of.)
Citric Acid.
This acid is found abundantly in lemon-juice and in lime-juice. It occurs
in commerce in the form of large crystals, which are soluble in less than
their own weight of water at 60°.
Commercial citric acid is sometimes mixed with tartaric acid. The
adulteration may be discovered by making a concentrated solution of the
acid and adding _acetate of potash_; crystals of bitartrate of potash will
separate if tartaric acid be present.
Citric acid is tribasic. It forms with silver a white insoluble salt,
containing 3 atoms of oxide of silver to 1 atom of citric acid. If the
citrate of silver be heated in a current of hydrogen gas, a part of the
acid is liberated and the salt is reduced to a citrate of _suboxide_ of
silver; which is of a red color. The action of white light in reddening
citrate of silver is shown by the author to be of a similar nature.
Cyanide of Potassium.
Symbol, K, C{2}N, or KCy. Atomic weight, 66.
This salt is a compound of cyanogen gas with the metal potassium. Cyanogen
is not an elementary body, like chlorine or iodine, but consists of carbon
and nitrogen united in a peculiar manner. Although a compound substance,
it reacts in the manner of an element, and is therefore (like _ammonium_,
previously described) an exception to the usual laws of chemistry. Many
other bodies of a similar character are known.
Ether.
Symbol, C{4}H{5}O. Atomic weight, 37.
Ether is obtained by distilling a mixture of sulphuric acid and alcohol.
If the formula of alcohol (C{4}H{6}O{2}) be compared with that of ether,
it will be seen to differ from it in the possession of an additional atom
of hydrogen and of oxygen: in the reaction, the sulphuric acid removes
these elements in the form of water, and by so doing converts one atom
of alcohol into an atom of ether. The term _sulphuric_ applied to the
commercial ether has reference only to the manner of its formation.
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