A Practical Manual of the Collodion Process, Giving in Detail a Method For Producing Positive and Negative Pictures on Glass and Paper. — John Shaqi
A Practical Manual of the Collodion Process, Giving in Detail a Method For Producing Positive and Negative Pictures on Glass and Paper.Humphrey, S. D. (Samuel Dwight)
Science
A Practical Manual of the Collodion Process, Giving in Detail a Method For Producing Positive and Negative Pictures on Glass and Paper.
Humphrey, S. D. (Samuel Dwight)
Ambrotype; Photography
This is an organic substance somewhat analogous to albumen, but differing
from it in properties. It is obtained by subjecting bones, hoofs, horns,
calves' feet, etc., to the action of boiling water. The jelly formed
on cooling is termed size, or when dried or cut into slices, _glue_.
Gelatine, as it is sold in the shops, is a pure form of glue. _Isinglass_
is gelatine prepared, chiefly in Russia, from the air-bladders of certain
species of sturgeon.
_Properties of Gelatine._--Gelatine softens and swells up in cold water,
but does not _dissolve_ until heated: the hot solution, on cooling, forms
a tremulous jelly. One ounce f cold water will retain about three grains
of isinglass without gelatinizing; but much depends upon the temperature,
a few degrees greatly affecting the result.
Gelatine forms no compound with oxide of silver analogous to the
albuminate of silver; which fact explains the difference in the
photographic properties of albumen and gelatine.
Glycerine.
Fatty bodies are resolved by treatment with an alkali into an acid--which
combines with the alkali, forming a _soap_,--and glycerine, remaining in
solution.
Pure glycerine, as obtained by Price's patent process of distillation,
is a viscid liquid of sp. gr. about 1·23; miscible in all proportions
with water and alcohol. It is peculiarly a neutral substance, exhibiting
no tendency to combine with acids or bases. It has little or no action
upon nitrate of silver in the dark, and reduces it very slowly even when
exposed to light.
Gold, Chloride of.
Symbol, AuCl{3}. Atomic weight, 303.
This salt is formed by dissolving pure metallic gold in nitro-hydrochloric
acid, and evaporating at a gentle heat. The solution affords deliquescent
crystals of a deep orange color.
Chloride of gold, in a state fit for photographic use may easily be
obtained by the following process:--Place a half-sovereign in any
convenient vessel, and pour on it half a drachm of nitric acid mixed with
two and a half drachms of hydrochloric acid and three drachms of water;
digest by a gentle heat, but do not _boil_ the acid, or much of the
chlorine will be driven off in the form of gas. At the expiration of a few
hours add fresh aqua-regia in quantity the same as at first, which will
probably complete the solution, but if not, repeat the process a third
time.
Lastly, neutralize the liquid by adding carbonate of soda until all
effervescence ceases, and a green precipitate forms; this is _carbonate of
copper_, which must be allowed several hours to separate thoroughly. The
solution then contains chloride of gold in a neutral state, and free from
copper and silver, with which the metallic gold is alloyed in the standard
coin of the realm.
The weight of a half-sovereign is about 61 grains, of which 56 grains are
pure gold. This is equivalent to 86 grains of chloride of gold, which will
therefore be the quantity contained in the solution.
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