A Practical Manual of the Collodion Process, Giving in Detail a Method For Producing Positive and Negative Pictures on Glass and Paper.Humphrey, S. D. (Samuel Dwight)
Science
A Practical Manual of the Collodion Process, Giving in Detail a Method For Producing Positive and Negative Pictures on Glass and Paper.
Humphrey, S. D. (Samuel Dwight)
Ambrotype; Photography
_Chemical properties._--Nitric acid is a powerful oxidizing agent; it
dissolves all the common metals, with the exception of gold and platinum.
Animal substances, such as the cuticle, nails, etc., are tinged of a
permanent yellow color, and deeply corroded by a prolonged application.
Nitric acid forms a numerous class of salts, all of which _are soluble
in water_. Hence its presence cannot be determined by any precipitating
re-agent, in the same manner as that of hydrochloric and sulphuric acid.
_Impurities of Commercial Nitric Acid._--These are principally _chlorine_
and _sulphuric acid_; also peroxide of nitrogen, which tinges the acid
yellow, as already described. Chlorine is detected by diluting the acid
with an equal bulk of distilled water, and adding a few drops of nitrate
of silver,--a _milkiness_, which is chloride of silver in suspension,
indicates the presence of chlorine. In testing for sulphuric acid, dilute
the nitric acid as before, and drop in _a single drop_ of solution of
chloride of barium; if sulphuric acid be present, an insoluble precipitate
of sulphate of baryta will be formed.
Nitrous Acid. (_See_ Silver, Nitrate of.)
Nitrate of Potash.
Symbol, KO NO{5}. Atomic weight, 102.
This salt, also termed _nitre_ or _saltpetre_, is an abundant natural
product, found effloresced upon the soil in certain parts of the East
Indies. It is also produced artificially in what are called nitre-beds.
Nitrate of potash is _an anhydrous salt_,--it contains simply nitric acid
and potash, without any water of crystallization; still, in many cases,
a little water is retained mechanically between the interstices of the
crystals, and therefore it is better to dry before use. This may be done
by laying it in a state of fine powder upon blotting-paper, close to a
fire, or upon a heated metallic plate.
Nitrate of Baryta.
Symbol, BaO NO{5}. Atomic weight, 131.
Nitrate of baryta forms octahedral crystals, which are anhydrous. It is
considerably less soluble than the chloride of barium, requiring 12 parts
of cold and 4 of boiling water for solution. It may be substituted for the
nitrate of lead in the preparation of protonitrate of iron.
Nitrate of Lead.
Symbol, PbO NO{5}. Atomic weight, 166.
Nitrate of lead is obtained by dissolving the metal, or the oxide of lead,
in _excess_ of nitric acid, diluted with 2 parts of water. It crystallizes
on evaporation in white anhydrous tetrahedra and octahedra, which are
hard, and decrepitate on being heated; they are soluble in 8 parts of
water at 60°.
Nitrate of lead forms with sulphuric acid, or soluble sulphates, a white
precipitate, which is the insoluble sulphate of lead. The _Iodide_ of lead
is also very sparingly soluble in water.
Nitrate of Silver. (_See_ Silver, Nitrate of.)
Nitro-Hydrochloric Acid.
Symbol, NO{4} + Cl.
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