A Practical Manual of the Collodion Process, Giving in Detail a Method For Producing Positive and Negative Pictures on Glass and Paper.Humphrey, S. D. (Samuel Dwight)
Science
A Practical Manual of the Collodion Process, Giving in Detail a Method For Producing Positive and Negative Pictures on Glass and Paper.
Humphrey, S. D. (Samuel Dwight)
Ambrotype; Photography
This liquid is the aqua-regia of the old alchemists. It is produced by
mixing nitric and hydrochloric acids: the oxygen contained in the former
combines with the hydrogen of the latter, forming water and liberating
chlorine, thus:--
NO{5} + HCl = NO{4} + HO + Cl.
The presence of free chlorine confers on the mixture the power of
dissolving gold and platinum, which neither of the two acids possesses
separately. In preparing aqua-regia it is usual to mix one part, by
measure, of nitric acid with four of hydrochloric acid, and to dilute
with an equal bulk of water. The application of a gentle heat assists the
solution of the metal; but if the temperature rises to the boiling point,
a violent effervescence and escape of chlorine takes place.
Oxygen.
Symbol, O. Atomic weight, 8.
Oxygen gas may be obtained by heating nitrate of potash to redness, but in
this case it is contaminated with a portion of nitrogen. The salt termed
chlorate of potash (the composition of which is closely analogous to that
of the nitrate, chlorine being substituted for nitrogen) yields abundance
of pure oxygen gas on the application of heat, leaving behind chloride of
potassium.
_Chemical Properties._--Oxygen combines eagerly with many of the chemical
elements, forming oxides. This chemical affinity however is not well
seen when the elementary body is exposed to the action of _oxygen in the
gaseous form_. It is the _nascent_ oxygen which acts most powerfully as
an oxidizer. By nascent oxygen is meant oxygen on the point of separation
from other elementary atoms with which it was previously associated; it
may then be considered to be in the liquid form, and hence it comes more
perfectly into contact with the particles of the body to be oxidized.
Illustrations of the superior chemical energy of nascent oxygen are
numerous, but none perhaps are more striking than the mild and gradual
oxidizing influence exerted by atmospheric air, as compared with the
violent action of nitric acid and bodies of that class which contain
oxygen loosely combined.
Oxymel.
This syrup of honey and vinegar is prepared as follows:--Take of
Honey 1 pound.
Acid, acetic, fortiss. (Beaufoy's acid) 11 drachms.
Water 13 drachms.
Stand the pot containing the honey in boiling water until a scum rises
to the surface, which is to be removed two or three times. Then add the
acetic acid and water, and skim once more if required. Allow to cool, and
it will be fit for use.
Potash.
Symbol, KO + HO. Atomic weight, 57.
Potash is obtained by separating the carbonic acid from carbonate of
potash by means of caustic lime. Lime is a more feeble base than potash,
but the carbonate of lime, being _insoluble_ in water, is at once formed
on adding milk of lime to a solution of carbonate of potash.
Public-domain text, read in full here on John Shaqi.
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