A Practical Manual of the Collodion Process, Giving in Detail a Method For Producing Positive and Negative Pictures on Glass and Paper.Humphrey, S. D. (Samuel Dwight)
Science
A Practical Manual of the Collodion Process, Giving in Detail a Method For Producing Positive and Negative Pictures on Glass and Paper.
Humphrey, S. D. (Samuel Dwight)
Ambrotype; Photography
_Preparation and Properties of Iodide of Silver._--Iodide of silver may be
formed in an analogous manner to the chloride, viz. by the direct action
of the vapor of iodine upon metallic silver, or by double decomposition
between solutions of iodide of potassium and nitrate of silver.
When prepared by the latter mode it forms an impalpable powder, the color
of which varies slightly with the manner of precipitation. If the iodide
of potassium be in excess, the iodide of silver falls to the bottom of the
vessel nearly white; but with an excess of nitrate of silver it is of a
straw-yellow tint. This point may be noticed, because the yellow salt is
the one adapted for photographic use, the other being insensible to the
influence of light.
Iodide of silver is tasteless and inodorous; insoluble in water and in
dilute nitric acid. It is scarcely dissolved by ammonia, which serves
to distinguish it from the chloride of silver, freely soluble in that
liquid. Hyposulphite of soda and cyanide of potassium both dissolve iodide
of silver; it is also soluble in solutions of the alkaline bromides and
iodides.
Silver, Fluoride of.
Symbol, AgF. Atomic weight, 127.
This compound differs from those just described in being soluble in
water. The dry salt fuses on being heated, and is reduced by a higher
temperature, or by exposure to light.
Silver, Sulphuret of.
Symbol, AgS. Atomic weight, 124.
This compound is formed by the action of sulphur upon metallic silver, or
of sulphuretted hydrogen, or hydrosulphate of ammonia, upon the silver
salts; the decomposition of hyposulphite of silver also furnishes the
black sulphuret.
Sulphuret of silver is insoluble in water, and nearly so in those
substances which dissolve the chloride, bromide, and iodide, such as
ammonia, hyposulphites, cyanides, etc.; but it dissolves in nitric acid,
being converted into soluble sulphate and nitrate of silver.
Silver, Nitrate of.
Symbol, AgO NO{5}. Atomic weight, 170.
Nitrate of silver is prepared by dissolving metallic silver in nitric
acid. Nitric acid is a powerfully acid and corrosive substance, containing
two elementary bodies united in definite proportions. These are nitrogen
and oxygen; the latter being present in greatest quantity.
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