A Practical Manual of the Collodion Process, Giving in Detail a Method For Producing Positive and Negative Pictures on Glass and Paper.Humphrey, S. D. (Samuel Dwight)
Science
A Practical Manual of the Collodion Process, Giving in Detail a Method For Producing Positive and Negative Pictures on Glass and Paper.
Humphrey, S. D. (Samuel Dwight)
Ambrotype; Photography
Nitric acid is a powerful solvent for the metallic bodies generally. To
illustrate its action in that particular, as contrasted with other acids,
place pieces of silver foil in two test-tubes, the one containing dilute
sulphuric, the other dilute nitric acid; on the application of heat a
violent action soon commences in the latter, but the former is unaffected.
In order to understand the cause of the difference, it must be borne in
mind that when a metallic substance dissolves in an acid, the nature of
the solution is unlike that of an _aqueous_ solution of salt or sugar.
If you take salt water, and boil it down until the whole of the water
has evaporated, you obtain the salt again, with properties the same as
at first; but if a similar experiment be made with a solution of silver
in nitric acid, the result is different: in that case you do not get
metallic silver on evaporation, but silver _combined with oxygen_ and
_nitric acid_, both of which are tightly retained, being, in fact, in a
state of chemical combination with the metal.
If we closely examine the effects produced by treating silver with nitric
acid, we find them to be of the following nature:--first, a certain
amount of oxygen is imparted to the metal, so as to form an _oxide_, and
afterwards this oxide dissolves in another portion of the nitric acid,
producing _nitrate_ of the oxide, or, as it is shortly termed, nitrate of
silver.
It is therefore the _instability_ of nitric acid, its proneness to part
with oxygen, which renders it superior to sulphuric acid in the experiment
of dissolving silver. Nitric acid stands high in the list of "oxidizing
agents," and it is important that the photographer should bear this fact
in mind.
_Properties of Nitrate of Silver._--In the preparation of nitrate of
silver, when the metal has dissolved, the solution is boiled down in order
to drive off the excess of nitric acid, and set aside to crystallize. The
salt, however, as so obtained is still acid to test-paper, and requires
either recrystallization, or a careful heating to about 300° Fahrenheit,
to render it perfectly neutral.
Pure nitrate of silver occurs in the form of white crystalline plates,
which are very heavy and dissolve readily in an equal weight of cold
water. The solubility is much lessened by the presence of free nitric
acid, and in the _concentrated_ nitric acid the crystals are almost
insoluble. Boiling alcohol takes up about one-fourth part of its weight
of the crystallized nitrate, but deposits nearly the whole on cooling.
Nitrate of silver has an intensely bitter and nauseous taste; acting as a
caustic, and corroding the skin by a prolonged application. Its aqueous
solution is perfectly neutral to test-paper.
Public-domain text, read in full here on John Shaqi.
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