A Practical Manual of the Collodion Process, Giving in Detail a Method For Producing Positive and Negative Pictures on Glass and Paper.Humphrey, S. D. (Samuel Dwight)
Science
A Practical Manual of the Collodion Process, Giving in Detail a Method For Producing Positive and Negative Pictures on Glass and Paper.
Humphrey, S. D. (Samuel Dwight)
Ambrotype; Photography
Sulphuric acid possesses intense chemical powers, and displaces the
greater number of ordinary acids from their salts. It _chars_ organic
substances, by removing the elements of water, and converts alcohol into
ether in a similar manner. The _strength_ of a given sample of sulphuric
acid may generally be calculated from its specific gravity, and a table is
given by Dr. Ure for that purpose.
_Impurities of Commercial Sulphuric Acid._--The liquid acid sold as _oil
of vitriol_ is tolerably constant in composition, and seems to be as well
adapted for photographic use as the _pure_ sulphuric acid, which is far
more expensive. The specific gravity should be about 1·836 at 60°. If
a drop, evaporated upon platinum foil, gives a fixed residue, probably
bisulphate of potash is present. A milkiness, on dilution, indicates
sulphate of lead.
_Test for Sulphuric Acid._--If the presence of sulphuric acid, or a
soluble sulphate, be suspected in any liquid, it is tested for by adding a
few drops of dilute solution of chloride of barium, or nitrate of baryta.
A white precipitate, _insoluble in nitric acid_, indicates sulphuric acid.
If the liquid to be tested is very acid, from nitric or hydrochloric acid,
it must be largely diluted before testing, or a crystalline precipitate
will form, caused by the sparing solubility of the chloride of barium
itself in acid solutions.
Sulphurous Acid.
Symbol, SO{2}. Atomic weight, 32.
This is a gaseous compound, formed by burning sulphur in atmospheric air
or oxygen gas; also by heating oil of vitriol in contact with metallic
copper, or with charcoal.
When an acid of any kind is added to hyposulphite of soda, sulphurous acid
is formed as a product of the decomposition of hyposulphurous acid, but it
afterwards disappears from the liquid by a secondary reaction, resulting
in the production of trithionate and tetrathionate of soda.
_Properties._--Sulphurous acid possesses a peculiar and suffocating odor,
familiar to all in the fumes of burning sulphur. It is a feeble acid, and
escapes with effervescence, like carbonic acid, when its salts are treated
with oil of vitriol. It is soluble in water.
_Water._
Symbol, H{2}O. Atomic weight, 9.
Water is an oxide of hydrogen, containing single atoms of each of the
gases.
_Distilled water_ is water which has been vaporized and again condensed:
by this means it is freed from earthy and saline impurities, which, not
being volatile, are left in the body of the retort. _Pure_ distilled water
leaves no residue on evaporation, and should remain perfectly clear on the
addition of nitrate of silver, _even when exposed to the light_; it should
also be neutral to test-paper.
The condensed water of steam-boilers sold as distilled water is apt to be
contaminated with oily and empyreumatic matter, which discolors nitrate of
silver, and is therefore injurious.
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