A practical treatise on the manufacture of perfumery : $b comprising directions for making all kinds of perfumes, sachet powders, fumigating materials, dentrifices, cosmetics, etc., etc., with a full account of the volatile oils, balsams, resins, and other natural and artificial perfume-substances, including the manufacture of fruit ethers, and tests of their purityDeite, C. (Carl)
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A practical treatise on the manufacture of perfumery : $b comprising directions for making all kinds of perfumes, sachet powders, fumigating materials, dentrifices, cosmetics, etc., etc., with a full account of the volatile oils, balsams, resins, and other natural and artificial perfume-substances, including the manufacture of fruit ethers, and tests of their purity
Deite, C. (Carl)
Cosmetics; Perfumes; Perfumes industry
Liquid storax contains styrol (10 to 15 per cent.), styracin, and
cinnamic acid (10 to 15 per cent.). Styrol or cinnamol seems to be
the most important carrier of the odor and taste of liquid storax. If
20 parts of liquid storax are subjected to distillation together with
15 parts of crystallized soda and 200 parts of water, the cinnamol
collects in the form of a yellowish, very mobile liquid upon the
distillate. By rectification it can be obtained colorless, but is
thereby partially converted into metastyrol, an isomeric, amorphous,
odorless, and tasteless substance which is solid at an ordinary
temperature. By exposure for some time to a heat of 608° F. it is
reconverted into styrol. Styrol (C_{8}H_{8}) forms a clear, colorless,
mobile liquid having an odor of benzine and naphthalene. Its specific
gravity is 0.924 and its boiling point lies at 294.8° F. In water it
is but sparingly soluble, but is miscible in all proportions with
anhydrous spirit of wine, chloroform, benzine, ether, and oils. It
stands in the same relation to cinnamic acid as benzol to benzoic acid,
and is formed by distilling a mixture of cinnamic acid and barium oxide.
Styracin is cinnyl cinnamate. On distilling liquid storax with water,
styrol passes over. If now from the residue the cinnamic acid be
withdrawn by means of soda-solution, and the resin, which remains
behind, be treated with cold spirit of wine, styracin is left, which
crystallizes from ether, hot alcohol, or benzol. It forms colorless,
odorless, and tasteless crystals which melt at 113° F. and remain for
a long time fluid after melting. It is insoluble in water, but soluble
in 25 parts cold, and 2 parts boiling, spirit of wine, as well as in 5
parts ether. By oxidizing substances it is converted into bitter almond
oil and benzoic acid, and by the action of potassium hydroxide it is
decomposed to cinnyl alcohol and cinnamic acid.
Good liquid storax should yield to 90 per cent. alcohol at least so
much soluble matter that the dried residue of the filtered alcoholic
solution amounts to 65 per cent. of the quantity of storax.
Ordinary liquid storax, which has not been stored too long, contains
10 to 20 per cent. of water and about the same quantity of impurities
(fragments of plant tissue) which remain behind on treatment with the
above-mentioned solvents.
Public-domain text, read in full here on John Shaqi.
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