A System of Instruction in the Practical Use of the Blowpipe: Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic CombinationsAnonymous
Science
A System of Instruction in the Practical Use of the Blowpipe: Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic Combinations
Anonymous
Blowpipe
Tin-oxides combine with carbonate of soda, in the flame of oxidation
upon platinum wire, with intumescence to a bulky and confused mass,
which is insoluble in more soda. Upon charcoal, in the reduction
flame, it is easily reduced to a metallic globule. Certain compounds
of tin-oxides, particularly if they contain tantalum, are by fusion
with carbonate of soda reduced with difficulty; but by the addition of
some borax, the reduction to the metallic state is easily effected.
Tin-oxides exposed to the oxidation flame, then moistened with a
solution of cobalt, and exposed again to the flame of oxidation, will
exhibit, after having completely cooled, a bluish-green color.
EIGHTH GROUP.--MERCURY, ARSENIC.
These two metals are volatilized at a temperature lower than that of a
red heat, and produce, therefore, no reactions with borax and
microcosmic salt. Their oxides are easily reduced to the metallic
state.
(_a._) _Mercury_ (Hg).--This metal occurs in nature chiefly combined
with sulphur as a bisulphide.
It occurs still more rarely in the metallic form, or combined with
silver, selenium, or chlorine.
Mercury, in the metallic state, has a strong lustre, and is liquid at
ordinary temperatures, whereby it is distinguished from any other
metal. It freezes at 40° and boils at 620°, but it evaporates at
common temperatures. Pure mercury is unalterable. Upon being exposed
to the air, it tarnishes only by admixture with other metals, turns
grey on the surface, and loses its lustre. It is soluble in cold
nitric acid and in concentrated hot sulphuric acid, but not in
hydrochloric acid.
([chi].) _Protoxide of Mercury_ (Hg^{2}O).--It is a black powder,
which is decomposed by ignition into metallic mercury and oxygen. By
digestion with certain acids, and particularly with caustic alkalies,
it is converted into metallic mercury and peroxide. Some neutral salts
of the protoxide are only partly soluble in water, as they are
converted into basic insoluble and acid soluble salts.
Protoxide of mercury is completely insoluble in hydrochloric acid. Its
neutral salts change blue litmus paper to red.
([beta].) _Peroxide of Mercury_ (HgO).--This oxide exists in two
allotropic modifications. One is of a brick-red color, and the other
is orange. Being exposed to heat, they turn black, but regain their
respective colors upon cooling. They are decomposed at a high
temperature into metallic mercury and oxygen. They yield with acids
their own peculiar salts.
Mercury, in the metallic form, can never be mistaken for any other
metal in consequence of its fluid condition at ordinary temperatures.
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