A System of Instruction in the Practical Use of the Blowpipe: Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic CombinationsAnonymous
Science
A System of Instruction in the Practical Use of the Blowpipe: Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic Combinations
Anonymous
Blowpipe
Exposed to the blowpipe flame, it is instantly volatilized. This is
also the case with it when combined with other metals. The oxides of
mercury are, in the oxidation and reduction flames, instantly reduced
and volatilized. They do not produce any alteration with fluxes, as
they are volatilized before the bead melts. Heated with carbonate of
soda in a glass tube closed at one end, they are reduced to metallic
mercury, which is volatilized, and condenses upon a cool portion of
the tube as a grey powder. By cautious knocking against the tube, or
by rubbing with a glass rod, this sublimate can be brought together
into one globule of metallic mercury. Compounds of mercury can be most
completely reduced by a mixture of neutral oxalate of potassa and
cyanide of potassium. If the substance under examination contains such
a small quantity of mercury that it cannot be distinguished by
volatilization, a strip of gold leaf may be attached to an iron wire,
and introduced during the experiment in the glass tube. The smallest
trace of mercury will whiten the gold leaf in spots.
(_b._) _Arsenic_ (As).--This metal occurs in considerable quantity in
nature, chiefly combined with sulphur or metals.
Arsenic, in the metallic state, is of a whitish-grey color, high
lustre, and is crystalline, of a foliated structure, and is so brittle
that it can be pulverized. It does not melt, but is volatilized at
356°. Its vapor has a strong alliaceous odor. Arsenic sublimes in
irregular crystals. By exposure to the air it soon tarnishes, and is
coated black. Being mixed with nitrate of potassa and inflamed, it
detonates with vehemence. Mixed with carbonate of potassa, it is
inflamed by a stroke of the hammer, and detonates violently.
Heated in oxygen gas, it is inflamed, and burns with a pale blue flame
to arsenious acid.
([beta].) _Arsenious Acid_ (AsO^{3}).--This acid crystallizes in
octahedrons, or, when fused, forms a colorless glass, which finally
becomes opaque and enamel-like, or forms a white powder. It sublimes
without change or decomposition. When heated for a longer while below
the temperature of sublimation, it melts into a transparent,
colorless, tough glass. The opaque acid is sparingly soluble in cold
water, and still more soluble in hot water. It is converted, by
continued boiling, into the transparent acid, which is much more
soluble in water. Arsenious acid is easily dissolved by caustic
potassa. It is also soluble in hydrochloric acid. This acid occurs
associated with antimonious acid, protoxide of tin, protoxide of lead,
and oxide of copper. It occurs likewise in very small quantity in
ferruginous mineral springs.
([gamma].)_Arsenic Acid_ (AsO^{5}) is a white mass, which readily
absorbs moisture and dissolves. It will not volatilize at a low red
heat, nor will it decompose. Exposed to a strong heat, it is
decomposed, yielding oxygen, and passing into arsenious acid.
_Reactions before the Blowpipe._
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