A System of Instruction in the Practical Use of the Blowpipe: Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic CombinationsAnonymous
Science
A System of Instruction in the Practical Use of the Blowpipe: Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic Combinations
Anonymous
Blowpipe
(_c._) _Gold_ (Au).--This metal occurs mostly in the metallic state,
but frequently mixed with ores, and with other metals. Gold
crystallizes in cubes and octahedrons, is of a beautiful yellow color,
great lustre, and is the most malleable and ductile of all the metals.
It melts at a higher temperature than copper, gives a green colored
light when fused, and contracts greatly when cooling. It does not
oxidize at ordinary temperatures, nor when heated much above them. It
is soluble in nitro-hydrochloric acid (_aqua regia_).
([chi].) _Protoxide of Gold_ (Au^{2}O).--This oxide is a dark violet
colored powder which is converted by a temperature of 540° into
metallic gold and oxygen. It is only soluble in aqua regia. Treated
with hydrochloric acid, it yields the chloride of gold and the metal.
With aqua ammonia, it yields the fulminating gold, which is a blue
mass and very explosive.
([chi].) _Peroxide of Gold_ (Au^{2}O^{3}).--This oxide is an
olive-green or dark brown powder, containing variable quantities of
water. Decomposed at 530°, it yields metallic gold and oxygen.
_Reactions before the Blowpipe._--Oxides of gold are reduced, in both
the oxidation and reduction flames, to the metal, which fuses to
grains.
_Borax_ does not dissolve it, but it is reduced to the metallic state
in this flux in either flame. The reduced metal fuses upon charcoal to
a grain.
_Microcosmic Salt_ presents the same reactions as borax.
When fused with soda, upon charcoal, the soda is absorbed, and the
gold remains as a metallic grain.
TENTH GROUP.--MOLYBDENUM, OSMIUM.
These metals are not volatile, and are infusible before the blowpipe;
but some of their oxides are volatile, and can be reduced to an
infusible metallic powder.
(_a._) _Molybdenum_ (Mo) occurs in the metallic state; also combined
with sulphur, or as molybdic acid combined with lead. It is a white,
brittle metal, and is unaltered by exposure to the air. When heated
until it begins to glow, it is converted into a brown oxide. Heated at
a continued dull red heat, it turns blue. At a higher temperature, it
is oxidized to molybdic acid, when it glimmers and smokes, and is
converted into crystallized molybdic acid upon the surface.
([chi].) _Protoxide of Molybdenum_ (MoO).--This oxide is a black
powder.
([chi].) _Deutoxide of Molybdenum_ (MoO^{2}).--This oxide is a dark
copper-colored crystalline powder.
_Reactions before the Blowpipe._--Metallic molybdenum, its protoxide
and binoxide, are converted in the oxidation flame into molybdic acid.
This acid fuses in the flame of oxidation to a brown liquid, which
spreads, volatilizes, and sublimes upon the charcoal as a yellow
powder, which appears crystalline in the vicinity of the assay. This
sublimate becomes white after cooling. Beyond this sublimate there is
visible a thin and not volatile ore of binoxide, after cooling; this
is of a dark copper-red color, and presenting a metallic lustre.
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