A System of Instruction in the Practical Use of the Blowpipe: Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic CombinationsAnonymous
Science
A System of Instruction in the Practical Use of the Blowpipe: Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic Combinations
Anonymous
Blowpipe
Heated in a glass tube, closed at one end, it melts to a brown mass,
vaporizes and sublimates to a white powder upon a cool portion of the
tube. Immediately above the assay, yellow crystals are visible; these
crystals are colorless after cooling, and the fused mass becomes light
yellow-colored and crystalline.
Upon platinum foil, in the flame of oxidation, it melts and vaporizes,
and becomes light yellow and crystalline after cooling. In the
reduction flame it becomes blue, and brown-colored if the heat is
increased.
Upon charcoal, in the reduction flame, it is absorbed by the charcoal;
and, with an increase of the temperature, it is reduced to the metal,
which remains as a grey powder after washing off the particles of
charcoal.
_Borax_ dissolves it, in the oxidation flame, upon platinum wire
easily, and in great quantity, to a clear yellow, which becomes
colorless while cooling. By the addition of more of the molybdenic
acid the bead is dark yellow, or red while hot, and opalescent when
cold. In the reduction flame, the color of the bead is changed to
brown and transparent. By the addition of more of the acid, it becomes
opaque.
_Microcosmic Salt_ dissolves it in the oxidation flame, upon platinum
wire, to a clear, yellowish-green bead, which becomes colorless after
cooling. In the reduction flame the bead is very dark and opaque, but
becomes of a bright green after cooling. This is the case likewise
upon charcoal.
_Carbonate of Soda_ dissolves it upon platinum wire in the oxidation
flame with intumescence, to a clear bead, which appears milk-white
after cooling. Upon charcoal the soda and the molybdic acid are
absorbed, the latter is reduced to the metallic state, the metal
remaining as a grey powder after washing off the particles of
charcoal. When molybdic acid, or any other oxide of this metal, is
exposed upon platinum wire, or with platinum tongs, to the point of
the blue flame, a yellowish-green color is communicated to the
external flame. If also any of the compounds of molybdenum are mixed
in the form of a powder with concentrated sulphuric acid and alcohol,
and the latter inflamed, the flame of the alcohol appears colored
green.
(_c._) _Osmium_ (Os).--This metal occurs associated with platinum. It
is of a bluish-grey color, and is very brittle. Ignited in the open
air, it is oxidized to volatile osmic acid, which is possessed of a
pungent smell, and affects the eyes. It communicates a bright white
color to the flame of alcohol. Osmium oxide (OsO^{2}) is converted in
the oxidation flame to osmic acid, which is volatilized with a
peculiar smell, leaving a sublimate.
In the reduction flame it is reduced to a dark-brown infusible
metallic powder. It produces no reactions with fluxes. Carbonate of
soda reduces it upon charcoal to an infusible metallic powder, which
appears, after washing off the particles of charcoal, of a dark-brown
color.
ELEVENTH GROUP.--PLATINUM, PALLADIUM, IRIDIUM, RHODIUM, RUTHENIUM.
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