A System of Instruction in the Practical Use of the Blowpipe: Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic CombinationsAnonymous
Science
A System of Instruction in the Practical Use of the Blowpipe: Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic Combinations
Anonymous
Blowpipe
* * * * *
BISMUTH.
* * * * *
Mineral. Native bismuth
Formula. Bi.
Behavior
(1) in glass-bulb. --
(2) in open tube. Fuses and is converted into a yellow oxide.
(3) on charcoal. Fuses to a bead and incrusts the charcoal with
oxide.
(4) in forceps. --
(5) in borax. The oxide formed upon charcoal gives the bismuth
reactions.
(6) in mic. salt. As in borax.
(7) with carb. soda. --
(8) Special reactions. --
* * * * *
Mineral. Bismuthine
Formula. BiS.
Behavior
(1) in glass-bulb. --
(2) in open tube. Fuses with ebullition and gives of S and SO^{2}.
(3) on charcoal. Fuses with much spirting and in the reducing
flame yields a metallic bead and incrusts the
charcoal with oxide.
(4) in forceps. --
(5) in borax. The oxide obtained upon charcoal gives the
bismuth reactions.
(6) in mic. salt. As in borax.
(7) with carb. soda. As alone on charcoal. The fused alkali gives the
sulphur reaction on silver.
(8) Special reactions. --
* * * * *
Mineral. Bismuthblende
Formula. [...Bi=]^{2}[...Si]^{3}.
Behavior
(1) in glass-bulb. Turns yellow and, when strongly heated, fuses.
(2) in open tube. --
(3) on charcoal. Fuses with ebullition to a brown globule forming
an incrustation of [...Bi=] on the charcoal.
(4) in forceps. I. Fuses with ease to a yellow bead, coloring
the outer flame bluish green, especially if
moistened with HCl. This color is due to
[.....P].
(5) in borax. Gives the bismuth and also an iron reaction.
(6) in mic. salt. As in borax, but leaves a silicious skeleton.
(7) with carb. soda. Fuses to a yellow mass. The bismuth is then
reduced to the metallic state and partially
volatilized, incrusting the charcoal beyond.
(8) Special reactions. --
* * * * *
Mineral. Tetradymite
Formula. Bi, Te, S.
Behavior
(1) in glass-bulb. Occasionally decrepitates and then fuses,
forming a greyish white sublimate immediately
above the mineral fragment.
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