A System of Instruction in the Practical Use of the Blowpipe: Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic CombinationsAnonymous
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A System of Instruction in the Practical Use of the Blowpipe: Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic Combinations
Anonymous
Blowpipe
(2) in open tube. Evolves SO and becomes white or yellow if
containing iron.
(3) on charcoal. V. In the reducing flame incrusts the charcoal
with ZnO; also with CdO, if that metal be
present.
(4) in forceps. --
(5) in borax. The roasted mineral gives a zinc reaction, and
sometimes a slight iron reaction.
(6) in mic. salt. As in borax.
(7) with carb. soda. As alone on charcoal. Moreover colors the flame
blue. The fused alkali gives a S reaction on
silver.
(8) Special reactions. --
* * * * *
Mineral. Red oxide of zinc
Formula. [.Zn].
Behavior
(1) in glass-bulb. --
(2) in open tube. --
(3) on charcoal. In the reducing flame forms a thin incrustation
of oxide of zinc on the charcoal.
(4) in forceps. V.
(5) in borax. Generally gives a manganese and slight iron
reaction in addition to that of zinc.
(6) in mic. salt. As in borax.
(7) with carb. soda. On charcoal, forms a thick incrustation of ZnO.
(8) Special reactions. With carbonate of soda and nitre on platinum
foil gives manganese reaction.
* * * * *
Mineral. Electric calamine
Formula. 2[.Zn]^{3}[...Si] + 3[.H]
Behavior
(1) in glass-bulb. Gives off water and becomes white and opaque.
(2) in open tube. --
(3) on charcoal. --
(4) in forceps. V.
(5) in borax. Dissolves to a clear glass, which cannot be
rendered opaque by the intermittent flame.
(6) in mic. salt. Dissolves to a clear glass, which becomes opaque
on cooling. Silica remains insoluble.
(7) with carb. soda. With carbonate of soda alone is infusible. With
2 parts of alkali and 1 of borax fuses to a
glass and sets free [.Zn], which incrusts the
charcoal.
(8) Special reactions. --
* * * * *
Mineral. Calamine
Formula. [.Zn][..C].
Behavior
(1) in glass-bulb. Gives off CO^{2} and becomes opaque.
(2) in open tube. --
(3) on charcoal. As the red oxide. Sometimes also gives a lead
incrustation.
(4) in forceps. V.
(5) in borax. Gives a zinc reaction and frequently an iron and
manganese reaction.
(6) in mic. salt. As in borax.
(7) with carb. soda. Forms a thick incrustation of zinc, sometimes
also of [.Pb] and [.Co].
(8) Special reactions. Dissolves with much effervescence in cold acid.
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