A System of Instruction in the Practical Use of the Blowpipe: Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic CombinationsAnonymous
Science
A System of Instruction in the Practical Use of the Blowpipe: Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic Combinations
Anonymous
Blowpipe
(3) on charcoal. Gives off fumes smelling strongly of selenium
and coloring the flame blue. In the reducing
flame fuses partially and incrusts the charcoal
with Se and PbO. After some time a black
infusible mass alone remains.
(4) in forceps. --
(5) in borax. The infusible residue obtained upon charcoal
gives an iron and sometimes copper and cobalt
reaction.
(6) in mic. salt. As in borax.
(7) with carb. soda. With carbonate of soda, oxalate of potash yields
a metallic bead, the fused alkali laid upon
silver and moistened produces a stain similar to
that produced by sulfur.
(8) Special reactions. --
* * * * *
Mineral. Jamesonite
Formula. [,Pb]^{3}[,,,Sb]^{2}.
Behavior
(1) in glass-bulb. Fuses and gives off some sulphur, sulphide of
antimony and antimony which condense in the neck
of the bulb.
(2) in open tube. Fuses and emits dense white fumes of SbO^{3},
which pass off and redden blue litmus paper.
(3) on charcoal. Fuses with great ease evolving much SbO^{3} and
PbO, which incrusts the charcoal around the
mineral. When the fumes have ceased, a small
bead of metallic lead remains.
(4) in forceps. --
(5) in borax. The yellow incrustation formed upon charcoal
gives the reaction of lead, and the white those
of antimony.
(6) in mic. salt. As in borax.
(7) with carb. soda. As alone on charcoal. The fused alkali gives the
sulphur reaction on silver.
(8) Special reactions. --
* * * * *
Mineral. Minium
Formula. Pb^{3}O^{4}.
Behavior
(1) in glass-bulb. --
(2) in open tube. --
(3) on charcoal. Is reduced first to litharge (PbO) and then to
metallic lead which forms the usual
incrustation.
(4) in forceps. Colors the outer flame blue.
(5) in borax. Gives the lead reactions.
(6) in mic. salt. As in borax.
(7) with carb. soda. As alone on charcoal.
(8) Special reactions. --
* * * * *
Mineral. Mendipite
Formula. PbCl + 2PbO.
Behavior
(1) in glass-bulb. Decrepitates slightly and assumes a yellow
color.
(2) in open tube. --
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