A System of Instruction in the Practical Use of the Blowpipe: Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic CombinationsAnonymous
Science
A System of Instruction in the Practical Use of the Blowpipe: Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic Combinations
Anonymous
Blowpipe
(3) on charcoal. Fuses readily and is reduced to metallic lead
with the evolution of acid fumes. Forms a white
incrustation of PbCl, and a yellow one of PbO.
(4) in forceps. As the preceding.
(5) in borax. As the preceding.
(6) in mic. salt. As in borax.
(7) with carb. soda. As alone on charcoal.
(8) Special reactions. Gives the chlorine reaction with CuO and
microcosmic salt.
* * * * *
Mineral. Cerusite
Formula. [.Pb][..C].
Behavior
(1) in glass-bulb. Decrepitates, gives off CO^{2}, turns yellow and
fuses.
(2) in open tube. --
(3) on charcoal. Is reduced to metallic lead, incrusting the
charcoal around with PbO.
(4) in forceps. As the preceding.
(5) in borax. Gives the lead reaction.
(6) in mic. salt. As in borax.
(7) with carb. soda. As alone on charcoal.
(8) Special reactions. In nitric acid dissolves with much
effervescence.
* * * * *
Mineral. Anglesite
Formula. [.Pb][...S].
Behavior
(1) in glass-bulb. Decrepitates and gives off a small quantity of
water.
(2) in open tube. --
(3) on charcoal. In the oxidizing flame fuses to a clear bead,
which becomes opaque on cooling. In reducing
flame is reduced with much ebullition to a
metallic bead and incrusts the charcoal around
with PbO.
(4) in forceps. As the preceding.
(5) in borax. Gives the lead reaction and occasionally a
slight iron and manganese reaction.
(6) in mic. salt. As in borax.
(7) with carb. soda. Is reduced yielding a metallic lead bead. The
fused alkaline mass gives a sulphur reaction on
silver.
(8) Special reactions. --
* * * * *
Mineral. Pyromorphite
Formula. PbCl + 3[.Pb]^{3}[.....P].
Behavior
(1) in glass-bulb. Decrepitates, and when strongly heated for some
time, gives a slight white sublimate of PbCl.
(2) in open tube. --
(3) on charcoal. In oxidizing flame fuses to a bead having a
crystalline surface on cooling, and forms a thin
film of PbCl on the charcoal In reducing flame
fuses without reduction and on cooling assumes a
polyhedral form. Incrusts the charcoal slightly
with PbO.
(4) in forceps. Fuses and colors the flame blue.
(5) in borax. --
(6) in mic. salt. --
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