A System of Instruction in the Practical Use of the Blowpipe: Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic CombinationsAnonymous
Science
A System of Instruction in the Practical Use of the Blowpipe: Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic Combinations
Anonymous
Blowpipe
_Arsenic_, when vaporized, may be known by its peculiar alliaceous
odor. Arsenic is vaporized from its metallic state, and likewise from
its alloys. Several compounds which contain arsenic will also sublime,
such as the arsenical cobalt. Place in the bulb a small piece of
arsenical cobalt or "fly-stone," and apply heat. The sulphide of
arsenic will first rise, but soon the arsenic will adhere to the sides
of the tube.
The metals tellurium and cadmium are susceptible of solution, but the
heat required is a high one. This is best done upon charcoal.
The _perchloride of mercury_ sublimes undecomposed in the bulb,
previously undergoing fusion.
The _protochloride of mercury_ likewise sublimes, but it does not
undergo fusion first, as is the case with the corrosive sublimate.
The _ammoniacal salts_ all are susceptible of sublimation, which they
do without leaving a residue. There are, however, several which
contain fixed acids, which latter are left in the bulb. This is
particularly the case with the phosphates and borates. A piece of red
litmus paper will readily detect the escaping ammonia, while its odor
will indicate its presence with great certainty. The halogen compounds
of mercury, we should have mentioned, also sublime, the red iodide
giving a yellow sublimate.
The bulb is also a convenient little instrument for the purpose of
heating those substances which phosphoresce, and likewise those salts
that decrepitate.
Should the above reactions not be readily discerned, it should not be
considered as an indication that the substances are not present, for
they are frequently expelled in such combinations that the above
reactions will not take place. This is often the case with sulphur,
selenium, arsenic, and tellurium. It frequently happens, likewise,
that these substances are in such combinations that heat alone will
not sublime them; or else two or more of them may arise together, and
thus complicate the sublimate, so that the eye cannot readily detect
either substance. Sometimes sulphur and arsenic will coat the tube
with a metal-like appearance, which is deceptive. This coating
presents a metallic lustre at its lower portion, but changing, as it
progresses upward, to a dark brown, light brown, orange or yellow;
this sublimate being due to combinations of arsenic and sulphur, which
compounds are volatilized at a lower temperature than metallic
arsenic.
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