A System of Instruction in the Practical Use of the Blowpipe: Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic CombinationsAnonymous
Science
A System of Instruction in the Practical Use of the Blowpipe: Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic Combinations
Anonymous
Blowpipe
MOLYBDENUM.--This metal, in powder, is infusible before the blowpipe.
If heated in the outer flame, it becomes gradually oxidized, and
incrusts the charcoal, at a small distance from the assay, with
molybdic acid, which, near the assay, forms transparent crystalline
scales, and is elsewhere deposited as a fine powder. The incrustation,
while hot, is of a yellow color, but becomes white after cooling. It
may be volatilized by heating with either flame, and leaves the
surface of the charcoal, when perfectly cooled, of a dark-red copper
color, with a metallic lustre, due to the oxide of molybdenum, which
has been formed by the reducing action of the charcoal upon the
molybdic acid. In the reducing flame, metallic molybdenum remains
unchanged.
SILVER.--This metal, when fused alone, and kept in this state for some
time, under a strong oxidizing flame, covers the charcoal with a thin
film of dark reddish-brown oxide. If the silver be alloyed with lead,
a yellow incrustation of the oxide of that metal is first formed, and
afterwards, as the silver becomes more pure, a dark red deposit is
formed on the charcoal beyond. If the silver contains a small quantity
of antimony, a white incrustation of antimonious acid is formed, which
becomes red on the surface if the blast be continued. And if lead and
antimony are both present in the silver, after the greater part of
these metals have been volatilized, a beautiful crimson incrustation
is produced upon the charcoal. This result is sometimes obtained in
fusing rich silver ores on charcoal.
SULPHIDES, CHLORIDES, IODIDES, AND BROMIDES.
In blowpipe experiments, it rarely occurs that we have to deal with
pure metals, which, if not absolutely non-volatile, are recognized by
the incrustation they form upon charcoal. Some compound substances,
when heated upon charcoal, form white incrustations, resembling that
formed by antimony, and which, when heated, may, in like manner, be
driven from place to place. Among these are certain sulphides, as
sulphide of potassium, and sulphide of sodium, which are formed by the
action of the reducing flame upon the sulphates of potassa and soda,
and are, when volatilized, reconverted into those sulphates, and as
such deposited on the charcoal. No incrustation is, however, formed,
until the whole of the alkaline sulphate has been absorbed into the
charcoal, and has parted with its oxygen. As sulphide of potassium is
more volatile than sulphide of sodium, an incrustation is formed from
the former sooner than from the latter of these salts, and is
considerably thicker in the former case. If the potash incrustation be
touched with the reducing flame, it disappears with a violet-colored
flame; and if a soda incrustation be treated in like manner, an
orange-yellow flame is produced.
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