A System of Instruction in the Practical Use of the Blowpipe: Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic CombinationsAnonymous
Science
A System of Instruction in the Practical Use of the Blowpipe: Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic Combinations
Anonymous
Blowpipe
If not too saturated, the cupriferous glass soon becomes nearly
colorless, but immediately on solidifying assumes a red color
and becomes opaque. By long continued blowing on charcoal, the
copper in the bead is reduced and separates out as a small
metallic bead, leaving the glass colorless. With the addition of
tin, the glass becomes of an opaque dull-red on cooling.
Behavior with Mic. Salt on Platinum wire
in the oxidizing flame.
With an equal proportion of oxide, this salt is not so strongly
colored as borax. A small amount imparts a green color in the
warm and a blue in the cold. With a very large addition of
oxide, the glass is opaque in the hot state, and after cooling
of a greenish-blue.
in the reducing flame.
A tolerably saturated glass assumes a dark green color under a
good flame, and on cooling becomes of an opaque brick-red, the
moment it solidifies. A glass containing but a small proportion
of the oxide becomes equally red and opaque on cooling, if
treated with tin upon charcoal.
* * * * *
15. Oxide of Mercury, HgO.
Behavior with Borax on Platinum wire
in the oxidizing flame.
No reaction.
in the reducing flame.
No reaction.
Behavior with Mic. Salt on Platinum wire
in the oxidizing flame.
No reaction.
in the reducing flame.
No reaction.
* * * * *
16. Oxide of Silver, AgO.
Behavior with Borax on Platinum wire
in the oxidizing flame.
The oxide is partly dissolved and partly reduced. In small
quantity, it colors the glass yellow while warm, the color
disappearing on cooling. In larger quantity, the glass is yellow
while warm, but during cooling becomes paler to a certain point,
and then again deeper. If reheated slightly, the glass becomes
opalescent.
in the reducing flame.
On charcoal the argentiferous glass becomes at first grey from
the reduced metal, but afterwards, when the silver is collected
into a bead, it becomes clear and colorless.
Behavior with Mic. Salt on Platinum wire
in the oxidizing flame.
Both the oxide and the metal afford a yellowish glass, which,
when containing much oxide becomes opaline, exhibiting a yellow
color by daylight and a red one by artificial light.
in the reducing flame.
As in borax.
* * * * *
17. Oxide of Platinum, PtO^{2}.
18. Oxide of Palladium, PdO^{2}.
19. Oxide of Rhodium, R^{2}O^{3}.
20. Oxide of Iridium, Ir^{2}O^{3}.
21. Oxide of Ruthenium, Ru^{2}O^{9}.
22. Oxide of Osmium OsO^{2}.
Behavior with Borax on Platinum wire
in the oxidizing flame.
Are reduced without being dissolved. The reduced metal, being
infusible, cannot however be collected into a bead.
in the reducing flame.
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