A System of Instruction in the Practical Use of the Blowpipe: Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic CombinationsAnonymous
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A System of Instruction in the Practical Use of the Blowpipe: Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic Combinations
Anonymous
Blowpipe
As in the oxidizing flame.
Behavior with Mic. Salt on Platinum wire
in the oxidizing flame.
As in borax.
in the reducing flame.
As in borax.
* * * * *
23. Oxide of Gold, Au^{2}O^{3}.
Behavior with Borax on Platinum wire
in the oxidizing flame.
Is reduced without being dissolved and can be collected into a
bead on charcoal.
in the reducing flame.
As in the oxidizing flame.
Behavior with Mic. Salt on Platinum wire
in the oxidizing flame.
As in borax.
in the reducing flame.
As in borax.
* * * * *
24. Titanic Acid, TiO^{2}
Behavior with Borax on Platinum wire
in the oxidizing flame.
Dissolves readily to a clear glass which, when but little acid
is present, is colorless, but when in larger proportion, yellow,
and, on cooling, colorless. When sufficiently saturated, it may
be rendered opaque with an intermittent flame, and with a still
larger addition of the acid becomes so spontaneously on cooling.
in the reducing flame.
In small proportion, it renders the glass yellow in larger
quantity dark-yellow or brown. A saturated bead assumes a
blue enamel-like appearance under an intermittent flame.
Behavior with Mic. Salt on Platinum wire
in the oxidizing flame.
Dissolves readily to a clear glass, which, when sufficiently
saturated, is yellow white hot, and becomes colorless on
cooling.
in the reducing flame.
The glass obtained in the oxidizing glame becomes yellow in the
hot state, but on cooling assumes a beautiful violet color. If
too saturated, this color is so deep as to appear opaque, but is
not enameline. If the titanic acid contains iron, the glass
becomes on cooling of a brownish-yellow or red color. The
addition of tin neutralizes the iron, and the glass then becomes
violet.
* * * * *
25. Tantalic Acid, TaO^{3}.
Behavior with Borax on Platinum wire
in the oxidizing flame.
Dissolves readily to a clear colorless glass, which, when
sufficiently saturated, may be rendered opaque with an
intermittent flame, and with a larger addition of the acid
becomes spontaneously enameline on cooling.
in the reducing flame.
As in the oxidizing flame.
Behavior with Mic. Salt on Platinum wire
in the oxidizing flame.
Dissolves readily to a clear glass, which, when it contains a
large proportion of the acid, is yellow while warm, but becomes
colorless on cooling.
in the reducing flame.
The glass obtained in the oxidizing flame undergoes no change,
nor does it, according to _H. Rose_, alter by the addition of
sulphate of iron.
* * * * *
26. Niobic Acid, Ni^{2}O{3}
Behavior with Borax on Platinum wire
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