A System of Instruction in the Practical Use of the Blowpipe: Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic CombinationsAnonymous
Science
A System of Instruction in the Practical Use of the Blowpipe: Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic Combinations
Anonymous
Blowpipe
The oxides of manganese fuse with microcosmic salt in the oxidation
flame, to a clear brownish-violet bead, which appears reddish-violet
while cooling. This bead does not become opaque when overcharged with
manganese. As long as it is kept in fusion a continued boiling or
effervescence takes place, produced by the expulsion of oxygen, in
consequence of the fact that the microcosmic salt cannot dissolve much
sesquioxide, while the rest is reduced to protoxide, is re-oxidated,
and instantly again reduced. If the manganese is present in such a
minute quantity as not to perceptibly tinge the bead, the color may be
made to appear by the contact of a crystal of nitre while hot. The
bead foams up upon the addition of the nitre, and the foam appears,
after cooling, of a rose-red or violet color. In the reduction flame
the bead sometimes becomes colorless.
The oxides of manganese fuse with carbonate of soda upon platinum
foil or wire, to a clear green bead, which appears bluish-green and
partially opaque when cold (manganate of soda NaO + MnO^{3}). A very
minute trace of manganese will produce this green color. The oxides of
manganese cannot be reduced upon charcoal with carbonate of soda
before the blowpipe. The soda is absorbed, and (MnO + Mn^{2}O^{3}) is
left.
GROUP FIFTH.--IRON, COBALT, NICKEL.
The oxides of this group are reduced to the metallic state when fused
with carbonate of soda upon charcoal in the reduction flame. Metals
when thus reduced form powders, are not fusible or volatile in the
blowpipe flame, but they are attracted by the magnet.
Furthermore, these oxides are not dissolved by carbonate of soda in
the oxidation flame, but they produce colored beads with borax and
microcosmic salt.
(_a._) _Iron._--It occurs in great abundance in nature. It is found in
several places in America in the metallic state, and it likewise
occurs in the same state in meteors. It occurs chiefly as the oxide
(red hematite, brown hematite, magnetic oxide, etc.), and frequently
in combination with sulphur. Iron also forms a constituent of the
blood.
Metallic iron is of a grey color, and presents the metallic lustre
vividly when polished. It is very ductile, malleable, and tenacious.
It is very hard at common temperatures, but soft and yielding at a red
heat.
In dry and cold air, iron does not oxidize, but when the air is dry
and moist, it oxidizes rapidly. This likewise takes place with great
rapidity when the metal is heated to redness. When submitted to a
white heat iron burns with brilliant scintillations.
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