A System of Instruction in the Practical Use of the Blowpipe: Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic CombinationsAnonymous
Science
A System of Instruction in the Practical Use of the Blowpipe: Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic Combinations
Anonymous
Blowpipe
_Protoxide of Iron_ (FeO).--This oxide does not occur pure in nature,
but in union with the peroxide of iron and other substances. It
presents the form of a black powder, and has some metallic lustre, is
brittle, and fuses at a high temperature to a vitreous looking mass.
It is attracted by the magnet, and of course is susceptible of
becoming magnetic itself. It forms with water a hydrate, but this
passes so rapidly into a state of higher oxidation, that it is
difficult to keep it in the pure state.
_Magnetic Oxide of Iron_ (FeO + Fe^{2}O^{3}).--This peculiar oxide is
of a dark color, and is magnetic, so that tacks or small nails adhere
to it when brought in contact with it. It is the variety of the oxide
termed "loadstone." It is found frequently crystallized in octahedrons
in Scandinavia and other places. Magnetic oxide of iron is produced
when red-hot iron is hammered.
_Sesquioxide of Iron_ (Fe^{2}O^{3}).--This oxide is found native in
great abundance as red hematite and specular iron, crystallized in the
rhombic form. In the crystalline state it is of a blackish-grey color,
and possessed of the metallic lustre. When powdered, it forms a
brownish-red mass. When artificially prepared, it presents the
appearance of a blood-red powder. It is not magnetic, and has less
affinity for acids than the protoxide. Its hydrate is found native as
brown hematite.
By exposing the peroxide of iron to the oxidation flame, it is not
acted upon, but in the reduction flame it becomes reduced to the
magnetic oxide.
The oxides of iron are dissolved by borax in the oxidation flame to a
clear dark-yellow or dark-red bead, which appears lighter while
cooling, and yellowish when cold. In the presence of a very small
quantity of iron, the bead appears colorless when cold. If the iron is
increased, the bead is opaque while cooling, and of a dirty
dark-yellow color when cold. In the reduction flame, and fused upon
platinum wire, the bead appears dark green (FeO + Fe^{2}O^{3}). By the
addition of some tin, and fused upon charcoal, the bead appears
bluish-green, or not unlike that of sulphate of iron.
Microcosmic salt dissolves the oxides of iron in the oxidation flame
to a clear bead, which, by the addition of a considerable quantity of
iron, becomes of an orange color while hot, but gets lighter while
cooling, presenting finally a greenish hue, and gradually becoming
lighter, till, when cold, it is colorless. If the iron is increased,
the hot bead presents a dark red color, but while cooling a
brownish-red, which changes to a dirty-green, and, when cold, to a
brownish-red color. The decrease of the color during the transition
from the hot to the cold state is still greater in the bead formed by
the microcosmic salt.
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