A System of Instruction in the Practical Use of the Blowpipe: Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic CombinationsAnonymous
Science
A System of Instruction in the Practical Use of the Blowpipe: Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic Combinations
Anonymous
Blowpipe
It disappears gradually in the flame of reduction, while a white smoke
sublimates upon the charcoal. This sublimate is yellow while hot, but
changes to white when cold. The cause of this is, that the oxide is
reduced, is volatilized, and re-oxidized, by going through the
external flame in the form of a metallic vapor.
Borax dissolves oxide of zinc in the flame of oxidation easily to a
clear bead, which is yellow while hot, and colorless when cold. The
bead becomes, by the addition of more oxide, enamelled, while cooling.
If the bead is heated with the intermittent flame, it is milk-white
when cold. When heated in the flame of reduction upon platinum wire,
the bead at first appears opaque, and of a greyish color, but becomes
clear again after a continued blast.
When heated upon charcoal in the reduction flame, it is reduced to a
metal; but, at the same moment, is volatilized, and sublimes as oxide
of zinc upon the charcoal, about one line's distance from the assay.
This is likewise the case with the microcosmic salt, except that it is
more easily volatilized in the reduction flame.
Carbonate of soda does not dissolve the oxide of zinc in the flame of
oxidation. In the reduction flame and upon charcoal, the oxide of zinc
is reduced to the metallic state, and is volatilized with a white
vapor of the zinc oxide, which sublimes on the charcoal and exhibits a
yellow color while hot, and which changes to white when cold. By a
strong heat the reduced zinc burns with a white flame.
Moistened with a solution of cobalt oxide, and heated strongly in the
flame of oxidation, zinc oxide becomes of a yellowish-green color
while hot, and changes to a beautiful green color when cold.
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