A System of Instruction in the Practical Use of the Blowpipe: Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic CombinationsAnonymous
Science
A System of Instruction in the Practical Use of the Blowpipe: Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic Combinations
Anonymous
Blowpipe
oxide of nickel is easily effected, while the reduced nickel fuses
with the tin.
The oxide of nickel is dissolved by microcosmic salt in the oxidation
flame to a clear bead, which appears reddish while hot, but yellow and
sometimes colorless when cooling. If a considerable quantity of nickel
be present the heated bead is of a brown color, but orange when
cooled. In the reduction flame, and upon platinum wire, the color of
the bead is orange when cold; but upon charcoal, and with the addition
of a little tin, the bead appears grey and opaque. After being
submitted to the blowpipe flame all the nickel is reduced, and the
bead becomes colorless.
Carbonate of soda does not affect it in the oxidation flame, but in
the reduction flame and upon charcoal, it is absorbed and reduced, and
remains, after washing off the carbon, as a white metallic powder,
which is infusible, and has a greater attraction for the magnet than
iron.
_Sesquioxide of Nickel_ (Ni^{2}O^{3}).--It is in the form of a black
powder, and does not combine with other substances, unless it is
reduced to the protoxide. It exhibits before the blowpipe the same
behavior as the protoxide.
GROUP SIXTH.--ZINC, CADMIUM, ANTIMONY, TELLURIUM.
The substances of this group can be reduced upon charcoal by fusion
with carbonate of soda, but the reduced metals are volatilized, and
cover the charcoal with sublimates.
(_a._) _Zinc_ (Zn).--This metal is found in considerable abundance,
but never occurs in the pure metallic state, but in combination with
other substances, chiefly as sulphide in zinc blende, as carbonate in
calamine, and as the silicate in the kieselzinc ore; also, with
sulphuric acid, the "vitriol of zinc."
Zinc is of a bluish-white color and metallic lustre, is crystalline
and brittle when heated 400°F., but malleable and ductile between 200°
and 300°. It will not oxidize in dry air, but tarnishes if exposed to
air containing moisture, first becomes grey, and then passes into the
white carbonate. It decomposes in water at a glowing heat. It is
dissolved by diluted acids, while hydrogen is eliminated. It melts at
about 775°, and distills when exposed to a white heat in a close
vessel. When heated over 1000° in the open air, it takes fire, and
burns with a bluish-white light, and with a thick white smoke of oxide
of zinc.
_Oxide of Zinc_ (ZnO).--In the pure state, oxide of zinc is a white
powder, infusible, and not volatile. It is readily soluble in acids
after being heated strongly. Its soluble neutral salts, when dissolved
in water, change blue litmus paper to red. Its salts, with organic
acids, are decomposed by ignition, and the carbonate of zinc remains.
The oxide of zinc turns yellow by being ignited in the oxidation
flame, but it is only visible by daylight; this color changes to white
when cold. It does not melt, but produces a strong light, and it is
not volatile.
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